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Enantioselective Synthesis of 2,4,5-Trisubstituted Tetrahydropyrans via Peptide-Catalyzed Michael Addition Followed by Kishi’s Reductive Cyclization
http://hdl.handle.net/10069/39289
http://hdl.handle.net/10069/392890b541c3a-d7aa-43bd-aaae-5edfa6e682c4
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2019_Het_99_989.pdf (355.1 kB)
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2019_Het_99_989si.pdf (605 KB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-07-03 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Enantioselective Synthesis of 2,4,5-Trisubstituted Tetrahydropyrans via Peptide-Catalyzed Michael Addition Followed by Kishi’s Reductive Cyclization | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ueda, Atsushi
× Ueda, Atsushi× Higuchi, Mei× Umeno, Tomohiro× Tanaka, Masakazu |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | An enantioselective synthesis of 2,4,5-trisubstituted tetrahydropyrans has been achieved in four steps from α,β-unsaturated ketones and dimethyl malonate by peptide-catalyzed asymmetric Michael addition and diastereoselective construction of tetrahydropyran rings by Kishi’s reductive cyclization as key steps. A variety of α,β-unsaturated ketones were converted to the 1,4-products with high enantioselectivities (83-98% ee). | |||||
書誌情報 |
HETEROCYCLES 巻 99, 号 2, p. 989-1002, 発行日 2018-11-22 |
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出版者 | ||||||
出版者 | 日本複素環化学研究所 | |||||
出版者別言語 | ||||||
Japan Institute of Heterocyclic Chemistry | ||||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03855414 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.3987/COM-18-S(F)63 | |||||
権利 | ||||||
権利情報 | © 2018 The Japan Institute of Heterocyclic Chemistry | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | HETEROCYCLES, 99(2), pp.989-1002; 2019 |