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High regioselectivity in electrochemical α-methoxylation of N-protected cyclic amines
http://hdl.handle.net/10069/16314
http://hdl.handle.net/10069/16314821e7af9-abd8-4481-aa16-fa2c01a7df19
名前 / ファイル | ライセンス | アクション |
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Tetra64_3935.pdf (247.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-04-03 | |||||
タイトル | ||||||
タイトル | High regioselectivity in electrochemical α-methoxylation of N-protected cyclic amines | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Cyclic amines | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Electrochemical oxidation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Regioselective | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Libendi, Samuel S.
× Libendi, Samuel S.× Demizu, Yosuke× Matsumura, Yoshihiro× Onomura, Osamu |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | N-Protecting groups of α-substituted cyclic amines strongly affected the regioselectivity in electrochemical methoxylation of these compounds. Namely, N-acyl derivatives were transformed into α′-methoxylated compounds, while N-cyano derivatives changed into α-methoxylated derivatives. Furthermore, Lewis acid catalyzed nucleophilic substitution of the α-methoxylated compounds protected with cyano group afforded α,α-disubstituted cyclic amines. | |||||
書誌情報 |
Tetrahedron 巻 64, 号 18, p. 3935-3942, 発行日 2008-04 |
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出版者 | ||||||
出版者 | Elsevier | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00404020 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00861787 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.tet.2008.02.060 | |||||
権利 | ||||||
権利情報 | Copyright c 2008 Elsevier Ltd All rights reserved. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Tetrahedron, 64(18), pp.3935-3942; 2008 |