Oxidation of adamantanes by oxygen was effectively achieved by use of sodium nitrite as a catalyst in trifluoroacetic acid (TFA) to give 1-adamantyl trifluoroacetates, from which adamantanols were obtained in good yields. A catalytic amount of sodium nitrite was essential and TFA was the best solvent among solvents examined for this oxidation.
雑誌名
Synlett
巻
15
ページ
2415 - 2418
発行年
2006-06
出版者
Thieme
ISSN
09365214
書誌レコードID
AA10731110
DOI
10.1055/s-2006-950422
権利
(c) Georg Thieme Verlag KG Stuttgart New York. All rights reserved.
Efficient Oxidation of Adamantanes by Sodium Nitrite with Molecular Oxygen in Trifluoroacetic Acid
Synlett15_2415.pdf
(104.12KB)
NAOSITEについて