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Singlet-oxygen photosensitizers with a tetrad structure and a single BODIPY chromophore: An evidence for transition state stabilization of intersystem crossing
http://hdl.handle.net/10069/00041941
http://hdl.handle.net/10069/00041941abf390b9-fa20-4853-806d-17109b325c83
名前 / ファイル | ライセンス | アクション |
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DP210_110963.pdf (932.8 kB)
Download is available from 2024/11/24.
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2022-12-26 | |||||
タイトル | ||||||
タイトル | Singlet-oxygen photosensitizers with a tetrad structure and a single BODIPY chromophore: An evidence for transition state stabilization of intersystem crossing | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Maki, Toshihide
× Maki, Toshihide× Zhou, Zheyang× Irie, Yukari× Matsunaga, Takahide× Onodera, Takae× Imamichi, Shoji× Sasaki, Yuka× Masutani, Mitsuko× Otaki, Hiroki× Sakuda, Eri× Tanaka, Yoshimasa× Murota, Hiroyuki |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Eleven tetrad Boron dipyrromethene (BODIPY) derivatives were synthesized and examined as singlet-oxygen photosensitizers (PSs). It was clearly shown that a charge shifted state (CSS) with a twisted π-bond makes a considerable contributed to the transition state (TS) stabilization at the minimum energy seam of crossing (MESX) for intersystem crossing (ISC). An EC50 of less than 10 nM was achieved for the G361 human melanoma cell line using one of the investigated PSs, which were only composed of 1st− and 2nd-period elements with compact structures. | |||||
書誌情報 |
Dyes and Pigments 巻 210, p. 110963, 発行日 2022-11-25 |
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出版者 | ||||||
出版者 | Elsevier Ltd | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 01437208 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.dyepig.2022.110963 | |||||
権利 | ||||||
権利情報 | ⓒ 2022 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Dyes and Pigments, 210, art. no. 110963; 2022 |