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N- and O-arylation of pyridin-2-ones with diaryliodonium salts: base-dependent orthogonal selectivity under metal-free conditions
http://hdl.handle.net/10069/40266
http://hdl.handle.net/10069/40266c1dc1cfe-8d2d-4572-9826-74c2bf5a178d
名前 / ファイル | ライセンス | アクション |
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CheSci11_8295.pdf (918.6 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-09-18 | |||||
タイトル | ||||||
タイトル | N- and O-arylation of pyridin-2-ones with diaryliodonium salts: base-dependent orthogonal selectivity under metal-free conditions | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Kuriyama, Masami
× Kuriyama, Masami× Hanazawa, Natsumi× Abe, Yusuke× Katagiri, Kotone× Ono, Shimpei× Yamamoto, Kosuke× Onomura, Osamu |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Metal-free N- and O-arylation reactions of pyridin-2-ones as ambident nucleophiles have been achieved with diaryliodonium salts on the basis of base-dependent chemoselectivity. In the presence of N,N-diethylaniline in fluorobenzene, pyridin-2-ones were very selectively converted to N-arylated products in high yields. On the other hand, the O-arylation reactions smoothly proceeded with the use of quinoline in chlorobenzene, leading to high yields and selectivities. In these methods, a variety of pyridin-2-ones in addition to pyridin-4-one and a set of diaryliodonium salts were accepted as suitable reaction partners. | |||||
書誌情報 |
Chemical Science 巻 11, 号 31, p. 8295-8300, 発行日 2020-08-21 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 20416520 | |||||
EISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 20416539 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/D0SC02516J | |||||
権利 | ||||||
権利情報 | Open Access Article. Published on 21 July 2020. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Chemical Science, 11(31), pp.8295-8300; 2020 |