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An efficient method for selective oxidation of 1,2-diols in water catalyzed by Me2SnCl2
http://hdl.handle.net/10069/33980
http://hdl.handle.net/10069/3398078b2cb30-f76e-4a68-807f-dd04aa6e0d19
名前 / ファイル | ライセンス | アクション |
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RSCAd3_19247.pdf (104.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-11-15 | |||||
タイトル | ||||||
タイトル | An efficient method for selective oxidation of 1,2-diols in water catalyzed by Me2SnCl2 | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
William, Julius M.
× William, Julius M.× Kuriyama, Masami× Onomura, Osamu |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Dimethyltin(iv)dichloride-catalyzed selective oxidation of 1,2-diols in water was achieved using dibromoisocyanuric acid (DBI) or Br2 as oxidants. The catalyst activates the 1,2-diol moiety through the formation of stannylene acetal in addition to enhancing selectivity. Various cyclic and acyclic 1,2-diol substrates have been selectively oxidized affording α-hydroxyketones in good to excellent yields. This method is safe and simple in operation. | |||||
書誌情報 |
RSC Advances 巻 3, 号 42, p. 19247-19250, 発行日 2013-11-14 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
EISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 20462069 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/c3ra42754d | |||||
権利 | ||||||
権利情報 | © 2013 The Royal Society of Chemistry. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | RSC Advances, 3(42), pp.19247-19250; 2013 |