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Reductive N–N coupling of NO molecules on transition metal complexes leading to N2O
http://hdl.handle.net/10069/28046
http://hdl.handle.net/10069/28046670bd966-7d29-421f-af5f-d3dc57d1c63f
名前 / ファイル | ライセンス | アクション |
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CCR256_468.pdf (1.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-03-08 | |||||
タイトル | ||||||
タイトル | Reductive N–N coupling of NO molecules on transition metal complexes leading to N2O | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Hyponitrite | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | N-N coupling | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Nitric oxide reductase (NOR) | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Nitrogen monoxide | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Nitrous oxide | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Arikawa, Yasuhiro
× Arikawa, Yasuhiro× Onishi, Masayoshi |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Nitric oxide reductase (NOR) type reactions (2NO + 2e- + 2H+ → N2O + H2O) on transition metal complexes not involving NO disproportionation (3NO → N2O + NO2) are reviewed. The former has little reported, although the latter is very common reaction. The formation of N2O indicates that N-N coupling of two NO molecules is an essential step. A few examples of N-N coupling on transition metal complexes have been structurally characterized, including several examples of hyponitrite (O-N{double bond, long}N-O)2- complexes and only one diruthenium complex bearing neutral (O{double bond, long}N-N{double bond, long}O) binding mode. Protonation or heating their complexes led to elimination of N2O. In the examination of the NOR-type reaction, only a few functional model complexes for the active site of the metalloenzyme have been developed. These complexes also showed NOR activity. Finally, an NO reduction cycle in the diruthenium system is described. | |||||
書誌情報 |
Coordination Chemistry Reviews 巻 256, 号 5-8, p. 468-478, 発行日 2012-03 |
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出版者 | ||||||
出版者 | Elsevier BV | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00108545 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00619249 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.ccr.2011.10.023 | |||||
権利 | ||||||
権利情報 | Copyright © 2011 Elsevier B.V. All rights reserved. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Coordination Chemistry Reviews, 256(5-8), pp.468-478; 2012 |