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Adamantyl-functionalized polymer monolith for capillary electrochromatography.
http://hdl.handle.net/10069/23030
http://hdl.handle.net/10069/23030bccfb415-332f-4ea7-bd3e-521d654e6c6a
名前 / ファイル | ライセンス | アクション |
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JCA1217_1501.pdf (190.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2010-03-02 | |||||
タイトル | ||||||
タイトル | Adamantyl-functionalized polymer monolith for capillary electrochromatography. | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Adamantane | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Basic solute | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Capillary electrochromatography | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Peak tailing | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Polymer-based monolith | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ohyama, Kaname
× Ohyama, Kaname× Fukahori, Yuki× Nakashima, Kenichiro× Sueyoshi, Tomoyuki× Kishikawa, Naoya× Kuroda, Naotaka |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | An adamantyl (ADM)-functionalized monolithic stationary phase was newly synthesized by a single-step copolymerization of 1-adamantyl-(alpha-trifluoromethyl) acrylate, ethylene dimethacrylate, and 2-acrylamido-2-methyl-1-propanesulfonic acid in order to prevent the peak tailing of basic solutes in capillary electrochromatography and was compared with butyl methacrylate (BMA)-based one. The ADM structure shields the negatively charged groups on the surface of monolith from basic solutes, resulting in better peak shapes than BMA-based monolithic stationary phase. As the monomers ratio decreased, the monolithic column had lower retention and higher column efficiency which was likely due to lower phase ratio and smaller globule size of monolith, respectively. The ADM-functionalized monolithic columns exhibited a good repeatability and reproducibility of column preparation with relative standard deviation values below 9% in the studied chromatographic parameters. | |||||
書誌情報 |
Journal of chromatography. A 巻 1217, 号 9, p. 1501-1505, 発行日 2010-02-26 |
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出版者 | ||||||
出版者 | Elsevier B.V. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00219673 | |||||
EISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1873-3778 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10985833 | |||||
PubMed番号 | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | PMID | |||||
関連識別子 | 20060530 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.chroma.2009.12.056 | |||||
権利 | ||||||
権利情報 | Copyright © 2009 Elsevier B.V. All rights reserved. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Journal of chromatography. A, 1217(9), pp.1501-1505; 2010 |