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PbO-B_2O_3系及びR_2O-PbO-B_2O_3系(R=K or Na)ガラス中のVO^<2+>の光吸収スペクトルとPb原子の存在形態の研究
http://hdl.handle.net/10069/23584
http://hdl.handle.net/10069/235846e15e6fe-2072-429d-8ddd-7eb2ac6a7f7b
名前 / ファイル | ライセンス | アクション |
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110002316784.pdf (437.2 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2010-08-20 | |||||
タイトル | ||||||
タイトル | PbO-B_2O_3系及びR_2O-PbO-B_2O_3系(R=K or Na)ガラス中のVO^<2+>の光吸収スペクトルとPb原子の存在形態の研究 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | PbO-B_2O_3 glasses | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | R_2O-PbO-B_2O_3 glasses | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Glass structure | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Optical spectra | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Vanadyl ion | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Color indicator | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Bonding mode (Pb and R (=K and Na)) | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
古賀, 秀人
× 古賀, 秀人× 小池, 隆× 内山, 休男× 羽坂, 雅之 |
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著者別名 | ||||||
姓名 | Koga, Hodeto | |||||
著者別名 | ||||||
姓名 | Koike, Takashi | |||||
著者別名 | ||||||
姓名 | Uchiyama, Yasuo | |||||
著者別名 | ||||||
姓名 | Hasaka, Masayuki | |||||
その他のタイトル | ||||||
その他のタイトル | Studies on Optical Absorption Spectra of VO^<2+> Ions in PbO-B_2O_3 and R_2O-PbO-B_2O_3(R=K or Na)Glasses and Bonding Mode of Pb Atoms in these Glasses | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The optical absorption spectra of VO2+ ions dissolved in PbO-B2O3 and R2O-PbO-B2O3 glasses (R=K or Na) have been measured. By using the spectral results, the bonding mode of Pb in the glasses has been disussed. Judging from the dependence of peak position for B*2-E*n transition on the glass composition, it is suggested that although Pb behaves as a network modifier in the glasses, a part of Pb contributes to the formation of glass network. This relation is discussed on the basis of the relation between the peak wave number and ratio of four-coordinated B atoms to the total B atoms (N4B). On the assumption that the Pb ratio used in the formation of the glass network is α(x-0.2) in xPb(1-x)B2O3 glasses and (x+y-0.2) in xR2OyPbO(1-x-y)B2O3 glasses, the value of α is calculated to be 2.04. | |||||
書誌情報 |
窯業協會誌 en : Journal of the Ceramic Association, Japan 巻 94, 号 1095, p. 1125-1130, 発行日 1986-11 |
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出版者 | ||||||
出版者 | 日本セラミックス協会 | |||||
出版者別言語 | ||||||
The Ceramic Society of Japan | ||||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00090255 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00245653 | |||||
権利 | ||||||
権利情報 | 社団法人日本セラミックス協会 | |||||
権利 | ||||||
権利情報 | 本文データは学協会の許諾に基づきCiNiiから複製したものである | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関係URI | ||||||
関連名称 | http://ci.nii.ac.jp/naid/110002316784/ | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 窯業協会誌, 94(1095), pp.1125-1130; 1986 |