WEKO3
アイテム
{"_buckets": {"deposit": "faa555a9-f102-4e1f-90df-451d792af894"}, "_deposit": {"created_by": 2, "id": "15952", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "15952"}, "status": "published"}, "_oai": {"id": "oai:nagasaki-u.repo.nii.ac.jp:00015952", "sets": ["1267"]}, "author_link": ["59714", "59713"], "item_3_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1978-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10", "bibliographicPageEnd": "90", "bibliographicPageStart": "83", "bibliographic_titles": [{"bibliographic_title": "長崎大学工学部研究報告"}, {"bibliographic_title": "Reports of the Faculty of Engineering, Nagasaki University", "bibliographic_titleLang": "en"}]}]}, "item_3_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Two different types of the polymers containing nucleic acid bases in backbone or in pendant groups were prepared. The polymers of the first type were polyureas obtained by the polyaddition reaction of uracil and adenine with hexamethylene diisocyanate (HMDI). The second type, that is cationic polyurethanes containing nucleic acid bases in pendant groups, were obtained by Menschutkin reaction of halogenated derivatives of uracil and adenine with a linear polyurethane containing, tertiary nitrogen atoms which was based on HMDI and N-methyldiethanolamine. Base-base interactions were studied for the polymers by UV and NMR spectra. A relatively high value of hypochromicity, ca. 19%, was observed for the mixture of the ionic polyurethane with uracil pendant and herring sperm DNA. Complementary hydrogen bonding interaction was detected for the mixture of the ionic polyurethane with adenine pendant and that with uracil pendant. Nonthrombogenic character of the polymers was examined according to the modified Lee-White method. The ionic polyurethanes with adenine and uracil pendant exhibited fairly good anti-clotting property.", "subitem_description_type": "Abstract"}]}, "item_3_description_64": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "長崎大学工学部研究報告, (10), pp.83-90; 1978", "subitem_description_type": "Other"}]}, "item_3_publisher_33": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "長崎大学工学部"}]}, "item_3_source_id_10": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00178418", "subitem_source_identifier_type": "NCID"}]}, "item_3_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "02860902", "subitem_source_identifier_type": "ISSN"}]}, "item_3_source_id_8": {"attribute_name": "EISSN", "attribute_value_mlt": [{"subitem_source_identifier": "18805574", "subitem_source_identifier_type": "ISSN"}]}, "item_3_text_63": {"attribute_name": "出版者別言語", "attribute_value_mlt": [{"subitem_text_value": "Faculty of Engineering, Nagasaki University"}]}, "item_3_version_type_16": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hiraoka, Kyoko"}], "nameIdentifiers": [{"nameIdentifier": "59713", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoyama, Tetsuo"}], "nameIdentifiers": [{"nameIdentifier": "59714", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-12-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "kogaku00_10_11.pdf", "filesize": [{"value": "584.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 584900.0, "url": {"label": "kogaku00_10_11.pdf", "url": "https://nagasaki-u.repo.nii.ac.jp/record/15952/files/kogaku00_10_11.pdf"}, "version_id": "3ba73eb6-a8d2-43c4-8fb4-3c989624a5d3"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Syntheses and Characterization of Polymers Containing Nucleic Acid Bases", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Syntheses and Characterization of Polymers Containing Nucleic Acid Bases"}]}, "item_type_id": "3", "owner": "2", "path": ["1267"], "permalink_uri": "http://hdl.handle.net/10069/23902", "pubdate": {"attribute_name": "公開日", "attribute_value": "2010-09-14"}, "publish_date": "2010-09-14", "publish_status": "0", "recid": "15952", "relation": {}, "relation_version_is_last": true, "title": ["Syntheses and Characterization of Polymers Containing Nucleic Acid Bases"], "weko_shared_id": -1}
Syntheses and Characterization of Polymers Containing Nucleic Acid Bases
http://hdl.handle.net/10069/23902
http://hdl.handle.net/10069/239024f554639-f6b4-45c7-820f-08cd2ef4338f
名前 / ファイル | ライセンス | アクション |
---|---|---|
kogaku00_10_11.pdf (584.9 kB)
|
|
Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2010-09-14 | |||||
タイトル | ||||||
タイトル | Syntheses and Characterization of Polymers Containing Nucleic Acid Bases | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
Hiraoka, Kyoko
× Hiraoka, Kyoko× Yokoyama, Tetsuo |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Two different types of the polymers containing nucleic acid bases in backbone or in pendant groups were prepared. The polymers of the first type were polyureas obtained by the polyaddition reaction of uracil and adenine with hexamethylene diisocyanate (HMDI). The second type, that is cationic polyurethanes containing nucleic acid bases in pendant groups, were obtained by Menschutkin reaction of halogenated derivatives of uracil and adenine with a linear polyurethane containing, tertiary nitrogen atoms which was based on HMDI and N-methyldiethanolamine. Base-base interactions were studied for the polymers by UV and NMR spectra. A relatively high value of hypochromicity, ca. 19%, was observed for the mixture of the ionic polyurethane with uracil pendant and herring sperm DNA. Complementary hydrogen bonding interaction was detected for the mixture of the ionic polyurethane with adenine pendant and that with uracil pendant. Nonthrombogenic character of the polymers was examined according to the modified Lee-White method. The ionic polyurethanes with adenine and uracil pendant exhibited fairly good anti-clotting property. | |||||
書誌情報 |
長崎大学工学部研究報告 en : Reports of the Faculty of Engineering, Nagasaki University 号 10, p. 83-90, 発行日 1978-01 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 02860902 | |||||
EISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18805574 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00178418 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 長崎大学工学部 | |||||
出版者別言語 | ||||||
Faculty of Engineering, Nagasaki University | ||||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 長崎大学工学部研究報告, (10), pp.83-90; 1978 |