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Synthesis and photophysical properties of butterfly-shaped dinuclear Pt(II) complex having NHC-based chelate ligands
http://hdl.handle.net/10069/39221
http://hdl.handle.net/10069/3922176527bd3-10ce-4e48-951c-3fa4c1e30d52
名前 / ファイル | ライセンス | アクション |
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ICA493_43.pdf (909.9 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-12-18 | |||||
タイトル | ||||||
タイトル | Synthesis and photophysical properties of butterfly-shaped dinuclear Pt(II) complex having NHC-based chelate ligands | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Dinuclear complex | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Platinum | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Pyridyl-NHC ligand | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Moon, Sangjoon
× Moon, Sangjoon× Horiuchi, Shinnosuke× Sakuda, Eri× Ito, Akitaka× Arikawa, Yasuhiro× Umakoshi, Keisuke |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A butterfly-shaped dinuclear Pt(II) complex having pyridyl-NHC chelate ligands and bridging Me2pz ligands was synthesized. The crystal structure of the Pt2 complex showed short intramolecular Pt?Pt distance (3.129?A) and unique packing structure containing one-dimensional infinite pore that was filled with solvent molecules. The absorbance was proportional to the concentration of Pt2 complex and no significant bands appeared even in high concentration (up to 100?μM). The Pt2 complex showed bluish-green emission (λmax?=?459?nm) in the solid state at 298?K (λex?=?330?nm). TD-DFT calculation revealed that the lowest-energy absorption bands are mainly assigned to the combination of metal-to-ligand charge transfer (MLCT) and ligand-to-ligand charge transfer (LLCT) transitions. | |||||
書誌情報 |
Inorganica Chimica Acta 巻 493, p. 43-48, 発行日 2019-07-01 |
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出版者 | ||||||
出版者 | Elsevier B.V. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00201693 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.ica.2019.04.045 | |||||
権利 | ||||||
権利情報 | c 2019 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Inorganica Chimica Acta, 493, pp.43-48; 2019 |