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Bridging-arylene effects on spectroscopic and photophysical properties of arylborane–dipyrrinato zinc(ii) complexes
http://hdl.handle.net/10069/00040526
http://hdl.handle.net/10069/000405268e63e183-4c52-486b-b072-017e931dc720
名前 / ファイル | ライセンス | アクション |
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RSCAd11_6259.pdf (870.6 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-03-02 | |||||
タイトル | ||||||
タイトル | Bridging-arylene effects on spectroscopic and photophysical properties of arylborane–dipyrrinato zinc(ii) complexes | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Takaki, Koyo
× Takaki, Koyo× Sakuda, Eri× Ito, Akitaka× Horiuchi, Shinnosuke× Arikawa, Yasuhiro× Umakoshi, Keisuke |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Novel bis(dipyrrinato)zinc(ii) derivatives having 4-[bis(2,4,6-trimethylphenyl)boryl]phenyl (ZnBph) or 4-[bis(2,4,6-trimethylphenyl)boryl]-2,3,5,6-tetramethylphenyl groups (ZnBdu) at the 5-position of the dipyrrinato ligands were designed and synthesized.InZnBphwith the smaller dipyrrinate-arylene and arylene-dimesitylboryl dihedral angles, an intramolecular charge transfer arising from the presence of the vacant p orbital on the boron atom participates in the ππ* excited state in character in contrast to the pure ππ* excited state ofZnBdu. The synergistic ππ*/ILCT excited state was weakly fluorescent, and the fluorescence was enhanced upon binding of fluoride to the boron atom. |
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書誌情報 |
RSC Advances 巻 11, 号 11, p. 6259-6267, 発行日 2021-02-03 |
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出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2046-2069 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/D0RA09029H | |||||
権利 | ||||||
権利情報 | © The Royal Society of Chemistry 2021. Open Access Article. Published on 03 February 2021. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | RSC Advances, 11(11), pp.6259-6267; 2021 |