WEKO3
アイテム
{"_buckets": {"deposit": "38330ac5-af20-4231-bb58-7faea7e6c9b1"}, "_deposit": {"created_by": 6, "id": "27388", "owners": [6], "pid": {"revision_id": 0, "type": "depid", "value": "27388"}, "status": "published"}, "_oai": {"id": "oai:nagasaki-u.repo.nii.ac.jp:00027388", "sets": ["21"]}, "author_link": ["121831", "121830", "121833", "121834", "121832"], "item_2_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-02-15", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "21", "bibliographicPageEnd": "3492", "bibliographicPageStart": "3489", "bibliographicVolumeNumber": "58", "bibliographic_titles": [{"bibliographic_title": "Chemical communications"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The formation and photophysical properties of two types of sandwich complexes supported by asymmetric Pt complex units having two different acetylide moieties are reported. The asymmetric Pt complex unit was obtained via acetylide metathesis reaction between two types of symmetric Pt complexes. The reversible acetylide exchange reaction was effectively suppressed by the incorporation of Cu ions to give unique chiral Pt4Cu3 and achiral Pt2Cu4Br4 sandwich complexes. The sandwich complexes exhibited moderate photoluminescence in the solid state, and their photophysical properties depended on the sandwich structures. These results suggest that asymmetric Pt complex units can give remarkable assembled structures by the concerted effect of labile coordination bonds and weak noncovalent interactions.", "subitem_description_type": "Abstract"}]}, "item_2_description_63": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "Chemical communications, 58(21), pp. 3489-3492; 2022", "subitem_description_type": "Other"}]}, "item_2_publisher_33": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_2_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1039/d1cc07108d", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_13": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": " © The Royal Society of Chemistry"}]}, "item_2_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "13597345", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_16": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Horiuchi, Shinnosuke"}], "nameIdentifiers": [{"nameIdentifier": "121830", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hiroiwa, Hirotaka"}], "nameIdentifiers": [{"nameIdentifier": "121831", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakuda, Eri"}], "nameIdentifiers": [{"nameIdentifier": "121832", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Arikawa, Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "121833", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Umakoshi, Keisuke"}], "nameIdentifiers": [{"nameIdentifier": "121834", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-02-15"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "CC58_3489.pdf", "filesize": [{"value": "455.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 455600.0, "url": {"label": "CC58_3489.pdf", "url": "https://nagasaki-u.repo.nii.ac.jp/record/27388/files/CC58_3489.pdf"}, "version_id": "605655bd-4fd5-4a0f-a9e7-0f6843776682"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "An asymmetric Pt diimine acetylide complex providing unique luminescent multinuclear sandwich complexes with Cu salts", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "An asymmetric Pt diimine acetylide complex providing unique luminescent multinuclear sandwich complexes with Cu salts"}]}, "item_type_id": "2", "owner": "6", "path": ["21"], "permalink_uri": "http://hdl.handle.net/10069/00041525", "pubdate": {"attribute_name": "公開日", "attribute_value": "2022-05-16"}, "publish_date": "2022-05-16", "publish_status": "0", "recid": "27388", "relation": {}, "relation_version_is_last": true, "title": ["An asymmetric Pt diimine acetylide complex providing unique luminescent multinuclear sandwich complexes with Cu salts"], "weko_shared_id": -1}
An asymmetric Pt diimine acetylide complex providing unique luminescent multinuclear sandwich complexes with Cu salts
http://hdl.handle.net/10069/00041525
http://hdl.handle.net/10069/00041525082eb60f-a8a9-4e92-85e5-46539dd82013
名前 / ファイル | ライセンス | アクション |
---|---|---|
CC58_3489.pdf (455.6 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2022-05-16 | |||||
タイトル | ||||||
タイトル | An asymmetric Pt diimine acetylide complex providing unique luminescent multinuclear sandwich complexes with Cu salts | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Horiuchi, Shinnosuke
× Horiuchi, Shinnosuke× Hiroiwa, Hirotaka× Sakuda, Eri× Arikawa, Yasuhiro× Umakoshi, Keisuke |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The formation and photophysical properties of two types of sandwich complexes supported by asymmetric Pt complex units having two different acetylide moieties are reported. The asymmetric Pt complex unit was obtained via acetylide metathesis reaction between two types of symmetric Pt complexes. The reversible acetylide exchange reaction was effectively suppressed by the incorporation of Cu ions to give unique chiral Pt4Cu3 and achiral Pt2Cu4Br4 sandwich complexes. The sandwich complexes exhibited moderate photoluminescence in the solid state, and their photophysical properties depended on the sandwich structures. These results suggest that asymmetric Pt complex units can give remarkable assembled structures by the concerted effect of labile coordination bonds and weak noncovalent interactions. | |||||
書誌情報 |
Chemical communications 巻 58, 号 21, p. 3489-3492, 発行日 2022-02-15 |
|||||
出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 13597345 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1039/d1cc07108d | |||||
権利 | ||||||
権利情報 | © The Royal Society of Chemistry | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Chemical communications, 58(21), pp. 3489-3492; 2022 |