WEKO3
アイテム
{"_buckets": {"deposit": "fa5e5e4b-4ea8-40ca-9324-2a3e6ec99ae9"}, "_deposit": {"created_by": 6, "id": "27813", "owners": [6], "pid": {"revision_id": 0, "type": "depid", "value": "27813"}, "status": "published"}, "_oai": {"id": "oai:nagasaki-u.repo.nii.ac.jp:00027813", "sets": ["11"]}, "author_link": ["123803", "123807", "123806", "123804", "123805"], "item_2_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-12-13", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "24", "bibliographicPageStart": "8856", "bibliographicVolumeNumber": "27", "bibliographic_titles": [{"bibliographic_title": "Molecules"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The chemical constituents of two root samples of Eupatorium heterophyllum DC. collected in Yunnan Province, China, were investigated. Five new oligomeric benzofurans (1–5), nine new benzofuran/dihydrobenzofuran derivatives, and a new thymol analog were isolated, and their structures were determined using extensive spectroscopic techniques, such as 1D and 2D NMR spectroscopy and DFT calculations of the CD spectra. Most of the new compounds, including oligomeric benzofurans (1–5), were obtained from only one of the root samples. Furthermore, this is the first example that produces oligomeric benzofurans in this plant. These results imply that diversification of secondary metabolites in E. heterophyllum is ongoing. Plausible biosynthetic pathways for 1–5 are also proposed.", "subitem_description_type": "Abstract"}]}, "item_2_description_63": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "Molecules, 27(24), art. no. 8856; 2022", "subitem_description_type": "Other"}]}, "item_2_publisher_33": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "MDPI"}]}, "item_2_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.3390/molecules27248856", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_13": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/)."}]}, "item_2_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1420-3049", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_16": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hu, Yiming"}], "nameIdentifiers": [{"nameIdentifier": "123803", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saito, Yoshinori"}], "nameIdentifiers": [{"nameIdentifier": "123804", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuo, Yosuke"}], "nameIdentifiers": [{"nameIdentifier": "123805", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Gong, Xun"}], "nameIdentifiers": [{"nameIdentifier": "123806", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tanaka, Takashi"}], "nameIdentifiers": [{"nameIdentifier": "123807", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-01-05"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "M27_8856.pdf", "filesize": [{"value": "2.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2500000.0, "url": {"label": "M27_8856.pdf", "url": "https://nagasaki-u.repo.nii.ac.jp/record/27813/files/M27_8856.pdf"}, "version_id": "a9a516e8-f938-426b-a08b-7be83c47a320"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Eupatorium heterophyllum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Asteraceae", "subitem_subject_scheme": "Other"}, {"subitem_subject": "benzofuran oligomer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "structure elucidation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hengduan mountain", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "New Benzofuran Oligomers from the Roots of Eupatorium heterophyllum Collected in China", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "New Benzofuran Oligomers from the Roots of Eupatorium heterophyllum Collected in China"}]}, "item_type_id": "2", "owner": "6", "path": ["11"], "permalink_uri": "http://hdl.handle.net/10069/00041947", "pubdate": {"attribute_name": "公開日", "attribute_value": "2023-01-05"}, "publish_date": "2023-01-05", "publish_status": "0", "recid": "27813", "relation": {}, "relation_version_is_last": true, "title": ["New Benzofuran Oligomers from the Roots of Eupatorium heterophyllum Collected in China"], "weko_shared_id": -1}
New Benzofuran Oligomers from the Roots of Eupatorium heterophyllum Collected in China
http://hdl.handle.net/10069/00041947
http://hdl.handle.net/10069/000419474d7a69aa-78cd-4f4f-8bb6-41d03b3d571a
名前 / ファイル | ライセンス | アクション |
---|---|---|
M27_8856.pdf (2.5 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2023-01-05 | |||||
タイトル | ||||||
タイトル | New Benzofuran Oligomers from the Roots of Eupatorium heterophyllum Collected in China | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Eupatorium heterophyllum | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Asteraceae | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | benzofuran oligomer | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | structure elucidation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Hengduan mountain | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Hu, Yiming
× Hu, Yiming× Saito, Yoshinori× Matsuo, Yosuke× Gong, Xun× Tanaka, Takashi |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The chemical constituents of two root samples of Eupatorium heterophyllum DC. collected in Yunnan Province, China, were investigated. Five new oligomeric benzofurans (1–5), nine new benzofuran/dihydrobenzofuran derivatives, and a new thymol analog were isolated, and their structures were determined using extensive spectroscopic techniques, such as 1D and 2D NMR spectroscopy and DFT calculations of the CD spectra. Most of the new compounds, including oligomeric benzofurans (1–5), were obtained from only one of the root samples. Furthermore, this is the first example that produces oligomeric benzofurans in this plant. These results imply that diversification of secondary metabolites in E. heterophyllum is ongoing. Plausible biosynthetic pathways for 1–5 are also proposed. | |||||
書誌情報 |
Molecules 巻 27, 号 24, p. 8856, 発行日 2022-12-13 |
|||||
出版者 | ||||||
出版者 | MDPI | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1420-3049 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.3390/molecules27248856 | |||||
権利 | ||||||
権利情報 | © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Molecules, 27(24), art. no. 8856; 2022 |