{"created":"2023-05-15T16:38:10.064774+00:00","id":11707,"links":{},"metadata":{"_buckets":{"deposit":"772c63be-bf3c-487a-bf4d-d5f12fe9ebda"},"_deposit":{"created_by":2,"id":"11707","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"11707"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00011707","sets":["14:21"]},"author_link":["44499","44505","44502","44498","44501","44508","44507","44503","44506","44504","44500","44497"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-03-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"141","bibliographicPageStart":"135","bibliographicVolumeNumber":"700","bibliographic_titles":[{"bibliographic_title":"Journal of Organometallic Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Reactions of (κ 3-polypyrazolylborato)(benzonitrile) rutheniums [RuCl{B(4-Ypz) 4}(PhCN) 2] {4-Ypz; 4-bromo-1-pyrazolyl (Y = Br) and 1-pyrazolyl (Y = H) groups} with terminal alkynes were studied. For the reactions with arylalkynes HC≡C(aryl) in the presence of NEt 3, (arylmethyl)(carbonyl)rutheniums [Ru{CH 2(aryl)}{B(4-Ypz) 4}(CO)(PhCN)] were yielded, indicating alkyne C≡C bond cleavage, whereas in the absence of NEt 3, arylalkyne polymerization proceeded instead of the (arylmethyl)ruthenium formation. Reasonably attributed reaction mechanism shows significant role of the vinylidene intermediates \"Ru=C=CH(aryl)\".","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Journal of Organometallic Chemistry, 700, pp.135-141; 2012","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier BV"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jorganchem.2011.11.031","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2011 Elsevier B.V. All rights reserved."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00704122","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022328X","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Onishi, Masayoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arikawa, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamaguchi, Mamoru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagano, Tomoe"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Inoue, Takayuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Terasoba, Atsunobu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsuo, Suguru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakagawa, Maki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawano, Hiroyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagaoka, Junko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Umakoshi, Keisuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Furukawa, Mutsuhisa"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-22"}],"displaytype":"detail","filename":"JOC700_135.pdf","filesize":[{"value":"212.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JOC700_135.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/11707/files/JOC700_135.pdf"},"version_id":"fda7a930-7bad-4487-9577-301ed8734196"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"1-Alkyne","subitem_subject_scheme":"Other"},{"subitem_subject":"Polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"Polypyrazolylborato","subitem_subject_scheme":"Other"},{"subitem_subject":"Ruthenium","subitem_subject_scheme":"Other"},{"subitem_subject":"Vinylidene","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reactions of (polypyrazolylborato)(benzonitrile)rutheniums with terminal alkynes: Reactivity changeover by triethylamine toward arylalkyne polymerization or formation of (arylmethyl)(carbonyl) complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reactions of (polypyrazolylborato)(benzonitrile)rutheniums with terminal alkynes: Reactivity changeover by triethylamine toward arylalkyne polymerization or formation of (arylmethyl)(carbonyl) complexes"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-03-09"},"publish_date":"2012-03-09","publish_status":"0","recid":"11707","relation_version_is_last":true,"title":["Reactions of (polypyrazolylborato)(benzonitrile)rutheniums with terminal alkynes: Reactivity changeover by triethylamine toward arylalkyne polymerization or formation of (arylmethyl)(carbonyl) complexes"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T19:01:50.958358+00:00"}