@article{oai:nagasaki-u.repo.nii.ac.jp:00012219, author = {Hirata, Shigeo and Kuriyama, Masami and Onomura, Osamu}, issue = {48}, journal = {Tetrahedron}, month = {Dec}, note = {Diastereoselective introduction of phosphono groups into l-proline derivatives at the 5-position was achieved with suitable selection of N-protecting group. N-Benzoyl-l-prolinate preferentially gave trans-phosphorylated products, which could be easily transformed into (S)-(pyrrolidin-2-yl)phosphonates. On the other hand, N-benzyloxycarbonyl-l-prolinate reacted with phosphite to give cis-substituted products, which could be easily transformed into (R)-(pyrrolidin-2-yl)phosphonates., Tetrahedron, 67(48), pp.9411-6416; 2011}, pages = {9411--9416}, title = {Facile synthesis of both enantiomers of (pyrrolidin-2-yl)phosphonate from l-proline}, volume = {67}, year = {2011} }