{"created":"2023-05-15T16:38:31.709768+00:00","id":12219,"links":{},"metadata":{"_buckets":{"deposit":"723a94a0-2ab7-48c5-acd4-39e2827ac487"},"_deposit":{"created_by":2,"id":"12219","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"12219"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00012219","sets":["73:74"]},"author_link":["45680","45678","45679"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"48","bibliographicPageEnd":"9416","bibliographicPageStart":"9411","bibliographicVolumeNumber":"67","bibliographic_titles":[{"bibliographic_title":"Tetrahedron"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Diastereoselective introduction of phosphono groups into l-proline derivatives at the 5-position was achieved with suitable selection of N-protecting group. N-Benzoyl-l-prolinate preferentially gave trans-phosphorylated products, which could be easily transformed into (S)-(pyrrolidin-2-yl)phosphonates. On the other hand, N-benzyloxycarbonyl-l-prolinate reacted with phosphite to give cis-substituted products, which could be easily transformed into (R)-(pyrrolidin-2-yl)phosphonates.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Tetrahedron, 67(48), pp.9411-6416; 2011","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier BV"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tet.2011.09.080","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2011 Elsevier Ltd. All rights reserved."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861787","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404020","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hirata, Shigeo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kuriyama, Masami"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Onomura, Osamu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-22"}],"displaytype":"detail","filename":"Tetra67_9411.pdf","filesize":[{"value":"220.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Tetra67_9411.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/12219/files/Tetra67_9411.pdf"},"version_id":"fe4e618f-a809-44cc-ab85-8c81818c27cb"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"(Pyrrolidin-2-yl)phosphonate","subitem_subject_scheme":"Other"},{"subitem_subject":"Arbusov reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"Diastereoselective phosphorylation","subitem_subject_scheme":"Other"},{"subitem_subject":"l-Proline","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Facile synthesis of both enantiomers of (pyrrolidin-2-yl)phosphonate from l-proline","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Facile synthesis of both enantiomers of (pyrrolidin-2-yl)phosphonate from l-proline"}]},"item_type_id":"2","owner":"2","path":["74"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-11-11"},"publish_date":"2011-11-11","publish_status":"0","recid":"12219","relation_version_is_last":true,"title":["Facile synthesis of both enantiomers of (pyrrolidin-2-yl)phosphonate from l-proline"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T18:59:47.162440+00:00"}