{"created":"2023-05-15T16:39:20.387254+00:00","id":13214,"links":{},"metadata":{"_buckets":{"deposit":"419932b4-1be5-4351-aa97-611c2f33591d"},"_deposit":{"created_by":2,"id":"13214","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"13214"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00013214","sets":["18:19"]},"author_link":["47920","47923","47922","47921"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-08-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"659","bibliographicPageStart":"654","bibliographicVolumeNumber":"374","bibliographic_titles":[{"bibliographic_title":"Inorganica Chimica Acta"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Two new ene-yne substituted 2,4-pentanedionatoruthenium(III) complexes formed by the Heck-like reactions in the course of the Sonogashira reactions. The two complexes are structural isomers; one is [Ru(E-1,4-mBSima)(dpm)2] and another is [Ru(E-2,4-mBSima)(dpm)2], where E-1,4-mBSima is E-3-(1,4-bis(trimethylsilyl)-1-butene-3-ynyl)-2,4-pentanedionate, E-2,4-mBSima is E-3-(2,4-bis(trimethylsilyl)-1-butene-3-ynyl)-2,4-pentanedionate, and dpm is dipivaloylmethanate (2,2,6,6-tetramethylheptan-3,5-dionate). Both of complexes have been characterized by 1H NMR and infrared spectroscopies, mass spectrometry, and electrochemistry. [Ru(E-1,4-mBSima)(dpm)2] has also been characterized by X-ray crystallography. The ruthenium(III) is coordinated in an octahedral arrangement by the oxygen atoms of three β-diketonate ligands. The dihedral angle between the 2,4-pentanedionato chelate ring and the ene-yne plane on the E-1,4-mBSima ligand is 91°. The ene-yne group in [Ru(E-1,4-mBSima)(dpm)2] is fixed either in the solution state suggested by the 1H NMR spectrum with no symmetry.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Inorganica Chimica Acta, 374(1), pp.654-659; 2011","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier BV"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.ica.2011.03.026","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2011 Elsevier B.V. All rights reserved."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10761133","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00201693","subitem_source_identifier_type":"ISSN"}]},"item_2_source_id_8":{"attribute_name":"EISSN","attribute_value_mlt":[{"subitem_source_identifier":"18733255","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hoshino, Yoshimasa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ozaki, Fumika"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Igarashi, Satoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yukawa, Yasuhiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-22"}],"displaytype":"detail","filename":"ICA374_654.pdf","filesize":[{"value":"192.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ICA374_654.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/13214/files/ICA374_654.pdf"},"version_id":"7d88a356-f985-446a-9201-ca5184f0d190"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"β-Diketone complex","subitem_subject_scheme":"Other"},{"subitem_subject":"1H NMR spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"Acetylenic compounds","subitem_subject_scheme":"Other"},{"subitem_subject":"DFT calculations","subitem_subject_scheme":"Other"},{"subitem_subject":"Ruthenium(III) complex","subitem_subject_scheme":"Other"},{"subitem_subject":"X-ray crystal","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Formation of novel ene-yne substituted β-diketonato ruthenium(III) complexes by the Heck-like reactions on coordinated ligand","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Formation of novel ene-yne substituted β-diketonato ruthenium(III) complexes by the Heck-like reactions on coordinated ligand"}]},"item_type_id":"2","owner":"2","path":["19"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-06-20"},"publish_date":"2011-06-20","publish_status":"0","recid":"13214","relation_version_is_last":true,"title":["Formation of novel ene-yne substituted β-diketonato ruthenium(III) complexes by the Heck-like reactions on coordinated ligand"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T18:55:10.162087+00:00"}