{"created":"2023-05-15T16:39:27.691167+00:00","id":13371,"links":{},"metadata":{"_buckets":{"deposit":"0d3be1d9-9fe9-40bc-b5ee-582439d4bdd7"},"_deposit":{"created_by":2,"id":"13371","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"13371"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00013371","sets":["73:74"]},"author_link":["48296","48294","48297","48295"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-03-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"1185","bibliographicPageStart":"1177","bibliographicVolumeNumber":"80","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Memory of chirality in the electrochemical oxidation of thiazolidine-4-carboxylic acid derivatives was observed. The relatively larger size of sulphur atom than the oxygen atom for oxazolidine-4-carboxylic acid derivative may slightly improved the enantioselectivities of the oxidized products. The bulkier penicillamine derivative 1c furnished 2c with much better enantioselectivity (91% ee) than that of the cysteine derivative 2b (85% ee). The presence of two extra dimethyl groups, for the penicillamine derivative improved the enantioselectivities of the thiazolidine derivatives from 85% ee to 91 % ee.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES, 80(2), pp.1177-1185; 2010","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Institute of Heterocyclic Chemistry"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3987/COM-09-S(S)101","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2010 The Japan Institute of Heterocyclic Chemistry Received."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03855414","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Onomura, Osamu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ng’aNg’a, Wanyoike  George"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumura, Yoshihiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kuriyama, Masami"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-22"}],"displaytype":"detail","filename":"Het80_1177.pdf","filesize":[{"value":"121.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Het80_1177.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/13371/files/Het80_1177.pdf"},"version_id":"8eac6de8-573c-4aee-b7ff-d458fe45fed6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Carbon-Carbon Bond Cleavage","subitem_subject_scheme":"Other"},{"subitem_subject":"Chiral N,O-Acetal","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrochemical Oxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"Memory of Chilarity","subitem_subject_scheme":"Other"},{"subitem_subject":"Thiazolidine-4-carboxylic Acid","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Memory of Chirality in the Electrochemical Oxidation of Thiazolidine-4-carboxylic Acid Derivatives","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Memory of Chirality in the Electrochemical Oxidation of Thiazolidine-4-carboxylic Acid Derivatives"}]},"item_type_id":"2","owner":"2","path":["74"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-07-28"},"publish_date":"2011-07-28","publish_status":"0","recid":"13371","relation_version_is_last":true,"title":["Memory of Chirality in the Electrochemical Oxidation of Thiazolidine-4-carboxylic Acid Derivatives"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T00:39:08.361122+00:00"}