@article{oai:nagasaki-u.repo.nii.ac.jp:00014221, author = {中尾, 英樹 and 新海, 征治 and 真鍋, 修}, issue = {25}, journal = {長崎大学工学部研究報告, Reports of the Faculty of Engineering, Nagasaki University}, month = {Jul}, note = {Flavins bearing an optically active substituent at N(10) (1-α and 1-b) were synthesized. As the substituent is sterically bulky, the rate constants for the oxidation of NADH model compounds which possibly proceeds via a face-to-face orientation were somewhat smaller than those of conventional flavins. We have found that the oxidation of optically active NADH model compounds by 1-b and tetra-O-acetylriboflavin occurs in an asymmetric manner. This is the first example for the in vitro asymmetric hydrogen transfer from NADH models to flavins., 長崎大学工学部研究報告, 15(25), pp.67-72; 1985}, pages = {67--72}, title = {光学活性基をもつフラビン類の合成とその不二水素移動反応}, volume = {15}, year = {1985} }