{"created":"2023-05-15T16:40:05.713335+00:00","id":14221,"links":{},"metadata":{"_buckets":{"deposit":"6eaa6302-534a-4e87-bc12-288f118fc461"},"_deposit":{"created_by":2,"id":"14221","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"14221"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00014221","sets":["14:15:1180:1193"]},"author_link":["51370","51373","51372","51374","51371","51369"],"item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Synthesis and Asymmetrie Hydrogen Transfer Reactions of Optically Active Flavins"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1985-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"25","bibliographicPageEnd":"72","bibliographicPageStart":"67","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"長崎大学工学部研究報告"},{"bibliographic_title":"Reports of the Faculty of Engineering, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Flavins bearing an optically active substituent at N(10) (1-α and 1-b) were synthesized. As the substituent is sterically bulky, the rate constants for the oxidation of NADH model compounds which possibly proceeds via a face-to-face orientation were somewhat smaller than those of conventional flavins. We have found that the oxidation of optically active NADH model compounds by 1-b and tetra-O-acetylriboflavin occurs in an asymmetric manner. This is the first example for the in vitro asymmetric hydrogen transfer from NADH models to flavins.","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学工学部研究報告, 15(25), pp.67-72; 1985","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"51372","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Nakao, Hideki"}]},{"nameIdentifiers":[{"nameIdentifier":"51373","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Shinkai, Seiji"}]},{"nameIdentifiers":[{"nameIdentifier":"51374","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Manabe, Osamu"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学工学部"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00178418","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"02860902","subitem_source_identifier_type":"ISSN"}]},"item_3_source_id_8":{"attribute_name":"EISSN","attribute_value_mlt":[{"subitem_source_identifier":"18805574","subitem_source_identifier_type":"ISSN"}]},"item_3_text_63":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"Faculty of Engineering, Nagasaki University"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"中尾, 英樹"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"新海, 征治"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"真鍋, 修"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-22"}],"displaytype":"detail","filename":"kogaku15_25_09.pdf","filesize":[{"value":"408.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kogaku15_25_09.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/14221/files/kogaku15_25_09.pdf"},"version_id":"f28f6e88-679c-47fd-b2b2-0d87b7239c25"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"光学活性基をもつフラビン類の合成とその不二水素移動反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"光学活性基をもつフラビン類の合成とその不二水素移動反応"}]},"item_type_id":"3","owner":"2","path":["1193"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-10-13"},"publish_date":"2010-10-13","publish_status":"0","recid":"14221","relation_version_is_last":true,"title":["光学活性基をもつフラビン類の合成とその不二水素移動反応"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T00:23:19.000997+00:00"}