@article{oai:nagasaki-u.repo.nii.ac.jp:00015155,
 author = {Ohyama, Kaname and Fukahori, Yuki and Nakashima, Kenichiro and Sueyoshi, Tomoyuki and Kishikawa, Naoya and Kuroda, Naotaka},
 issue = {9},
 journal = {Journal of chromatography. A},
 month = {Feb},
 note = {An adamantyl (ADM)-functionalized monolithic stationary phase was newly synthesized by a single-step copolymerization of 1-adamantyl-(alpha-trifluoromethyl) acrylate, ethylene dimethacrylate, and 2-acrylamido-2-methyl-1-propanesulfonic acid in order to prevent the peak tailing of basic solutes in capillary electrochromatography and was compared with butyl methacrylate (BMA)-based one. The ADM structure shields the negatively charged groups on the surface of monolith from basic solutes, resulting in better peak shapes than BMA-based monolithic stationary phase. As the monomers ratio decreased, the monolithic column had lower retention and higher column efficiency which was likely due to lower phase ratio and smaller globule size of monolith, respectively. The ADM-functionalized monolithic columns exhibited a good repeatability and reproducibility of column preparation with relative standard deviation values below 9% in the studied chromatographic parameters., Journal of chromatography. A, 1217(9), pp.1501-1505; 2010},
 pages = {1501--1505},
 title = {Adamantyl-functionalized polymer monolith for capillary electrochromatography.},
 volume = {1217},
 year = {2010}
}