{"created":"2023-05-15T16:40:46.034175+00:00","id":15156,"links":{},"metadata":{"_buckets":{"deposit":"9454fd8f-4e23-4864-95fa-37cf4a36fa4b"},"_deposit":{"created_by":2,"id":"15156","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"15156"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00015156","sets":["175:315"]},"author_link":["55715","55714","55716","55713"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-03-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"846","bibliographicPageStart":"841","bibliographicVolumeNumber":"80","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A divergent synthesis of three sulfate derivatives of lamellarin α, namely, lamellarin α 13-sulfate (2), 20-sulfate (1), and 13,20-disulfate (4) has been achieved via a common intermediate (6) in which 13-OH and 20-OH of the lamellarin core are differentially protected by MOM and benzyl groups, respectively. Compound (6) in turn was prepared using sequential Suzuki-Miyaura coupling of 3,4-dihydroxypyrrole bistriflate (7) as a key reaction.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES, 80(2), pp.841-846; 2010","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本複素環化学研究所"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3987/COM-09-S(S)100","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2010 The Japan Institute of Heterocyclic Chemistry"}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03855414","subitem_source_identifier_type":"ISSN"}]},"item_2_text_62":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"Japan Institute of Heterocyclic Chemistry"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Iwao, Masatomo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fukuda, Tsutomu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Saeki, Sho"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohta, Takeshi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-23"}],"displaytype":"detail","filename":"Het80_841.pdf","filesize":[{"value":"827.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Het80_841.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/15156/files/Het80_841.pdf"},"version_id":"9a4c4e21-3443-485a-98ef-f21fa46b1231"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Lamellarin α 13-Sulfate","subitem_subject_scheme":"Other"},{"subitem_subject":"Lamellarin α 20-Sulfate","subitem_subject_scheme":"Other"},{"subitem_subject":"Lamellarin α 13,20-Disulfate","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Divergent Synthesis of Lamellarin α 13-Sulfate, 20-Sulfate, and 13,20-Disulfate","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Divergent Synthesis of Lamellarin α 13-Sulfate, 20-Sulfate, and 13,20-Disulfate"}]},"item_type_id":"2","owner":"2","path":["315"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-03-03"},"publish_date":"2010-03-03","publish_status":"0","recid":"15156","relation_version_is_last":true,"title":["Divergent Synthesis of Lamellarin α 13-Sulfate, 20-Sulfate, and 13,20-Disulfate"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T00:11:15.298334+00:00"}