{"created":"2023-05-15T16:41:07.469510+00:00","id":15654,"links":{},"metadata":{"_buckets":{"deposit":"4b22a931-fc0b-4f0f-b9c9-d0a63e3747ae"},"_deposit":{"created_by":2,"id":"15654","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"15654"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00015654","sets":["14:21"]},"author_link":["58218","58220","58222","58223","58219","58216","58217","58221"],"item_2_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Studies on Optical Absorption Spectra of VO^<2+> Ions in PbO-B_2O_3 and R_2O-PbO-B_2O_3(R=K or Na)Glasses and Bonding Mode of Pb Atoms in these Glasses"}]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1986-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1095","bibliographicPageEnd":"1130","bibliographicPageStart":"1125","bibliographicVolumeNumber":"94","bibliographic_titles":[{"bibliographic_title":"窯業協會誌"},{"bibliographic_title":"Journal of the Ceramic Association, Japan","bibliographic_titleLang":"en"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The optical absorption spectra of VO2+ ions dissolved in PbO-B2O3 and R2O-PbO-B2O3 glasses (R=K or Na) have been measured.  By using the spectral results, the bonding mode of Pb in the glasses has been disussed.  Judging from the dependence of peak position for B*2-E*n transition on the glass composition, it is suggested that although Pb behaves as a network modifier in the glasses, a part of Pb contributes to the formation of glass network.  This relation is discussed on the basis of the relation between the peak wave number and ratio of four-coordinated B atoms to the total B atoms (N4B).  On the assumption that the Pb ratio used in the formation of the glass network is α(x-0.2) in xPb(1-x)B2O3 glasses and (x+y-0.2) in xR2OyPbO(1-x-y)B2O3 glasses, the value of α is calculated to be 2.04.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"窯業協会誌, 94(1095), pp.1125-1130; 1986","subitem_description_type":"Other"}]},"item_2_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"58220","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Koga, Hodeto"}]},{"nameIdentifiers":[{"nameIdentifier":"58221","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Koike, Takashi"}]},{"nameIdentifiers":[{"nameIdentifier":"58222","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Uchiyama, Yasuo"}]},{"nameIdentifiers":[{"nameIdentifier":"58223","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Hasaka, Masayuki"}]}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本セラミックス協会"}]},"item_2_relation_42":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://ci.nii.ac.jp/naid/110002316784/"}]}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"社団法人日本セラミックス協会"},{"subitem_rights":"本文データは学協会の許諾に基づきCiNiiから複製したものである"}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00245653","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00090255","subitem_source_identifier_type":"ISSN"}]},"item_2_text_62":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"The Ceramic Society of Japan"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"古賀, 秀人"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小池, 隆"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"内山, 休男"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"羽坂, 雅之"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-23"}],"displaytype":"detail","filename":"110002316784.pdf","filesize":[{"value":"437.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"110002316784.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/15654/files/110002316784.pdf"},"version_id":"9ae34a49-6780-495b-b08e-775ef894ea14"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"PbO-B_2O_3 glasses","subitem_subject_scheme":"Other"},{"subitem_subject":"R_2O-PbO-B_2O_3 glasses","subitem_subject_scheme":"Other"},{"subitem_subject":"Glass structure","subitem_subject_scheme":"Other"},{"subitem_subject":"Optical spectra","subitem_subject_scheme":"Other"},{"subitem_subject":"Vanadyl ion","subitem_subject_scheme":"Other"},{"subitem_subject":"Color indicator","subitem_subject_scheme":"Other"},{"subitem_subject":"Bonding mode (Pb and R (=K and Na))","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"PbO-B_2O_3系及びR_2O-PbO-B_2O_3系(R=K or Na)ガラス中のVO^<2+>の光吸収スペクトルとPb原子の存在形態の研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"PbO-B_2O_3系及びR_2O-PbO-B_2O_3系(R=K or Na)ガラス中のVO^<2+>の光吸収スペクトルとPb原子の存在形態の研究"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-08-20"},"publish_date":"2010-08-20","publish_status":"0","recid":"15654","relation_version_is_last":true,"title":["PbO-B_2O_3系及びR_2O-PbO-B_2O_3系(R=K or Na)ガラス中のVO^<2+>の光吸収スペクトルとPb原子の存在形態の研究"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T19:11:15.642067+00:00"}