@article{oai:nagasaki-u.repo.nii.ac.jp:00015658,
 author = {小山田, 了三 and 古賀, 秀人 and 星野, 朝則},
 issue = {1073},
 journal = {窯業協會誌, Journal of the Ceramic Association, Japan},
 month = {Jan},
 note = {PbO-SiO2系及びPbO-SiO2-K2O-Na2O系ガラス中のMn3+イオンの光吸収スペクトルとガラスの屈折率を測定し、ガラス組成と吸収ピーク波数及び屈折率の関係を調べた。PbO-SiO2系にMnO2を添加したガラス中のMn3+の吸収ピーク波数はMnO2添加量が増加するとともに低波数側へシフトした。屈折率はMnO2添加量が1.0mol%まではほぼ一定となった。PbO-SiO2-K2O-Na2O系ガラス中のMn3+の吸収ピーク波数は[K2O]/[K2O+Na2O]の値の増加とともに低波数側へシフトし、混合アルカリ効果ははっきりとは現れない。屈折率は[K2O]/[K2O+Na2O]の値の増加とともに直線的に減少し、混合アルカリ効果は明確には認められない。, Absorption spectra of Mn3+ ions in PbO-SiO2 and PbO-SiO2-K2O-Na2O glasses and refractive indices of these glasses were measured, and the effect of chemical composition was studied.  The peak wave numbers of Mn3+ ion shifted toward the lower wave numbers with increasing Mno2 addition in PbO-SiO2 glasses.  The refractive indices of PbO-SiO2 glasses were nearly constant.  The peak wave numbers of Mn3+ ions in PbO-SiO2-K2O-Na2O glasses shifted toward the lower wave numbers with increasing [K2O]/[K2O+Na2O] ratio.  The mixed alkali effect was not observed in the relation between peak wave number of Mn3+ and composition.  The refractive indices shifted linearly toward the lower values with increasing [K2O]/[K2O+Na2O] ratio.  No mixed alkali effect was observed clearly in the refractive index., 窯業協会誌, 93(1073), pp.58-62; 1985},
 pages = {58--62},
 title = {PbO-SiO_2及びPbO-SiO_2-K_2O-Na_2O系ガラス中のMn^<3+>イオンの光吸収スペクトル及びガラスの屈折率},
 volume = {93},
 year = {1985}
}