@article{oai:nagasaki-u.repo.nii.ac.jp:00001570, author = {KOUNO, Isao and BABA, Naosuke and HASHIMOTO, Miwa and KAWANO, Nobusuke and TAKAHASHI, Masakatsu and KANETO, Hiroshi and YANG, Chun-Shu and SATO, Sadao}, issue = {9}, journal = {Chemical & Pharmaceutical Bulletin}, month = {Sep}, note = {Three new sesquiterpene lactones, majucin (3), neomajucin (4), and 2, 3-dehydroneomajucin (5), have been isolated from the pericarps of Chineses Illicium majus, which is a toxic plant. The spectral features of compounds 3 and 4 were similar to those of anisatin (1), a convulsant from Japanese star anise. The structure of neomajucin (4) was determined by an X-ray crystallographic analysis, and the structures of the other compounds were deduced from the 1H- and 13C-nuclear magnetic resonance spectral data, aided by an extensive analysis of the 1H-1H, 13C-1H, and 13H-1H long-range two dimensional shift-correlated spectra, on the basis of the structure of neomajucin. Only neomajucin exhibited picrotoxin-like toxicity, amounting to one-tenth of that of anisatin., Chemical & Pharmaceutical Bulletin, 37(9), pp.2448-2451; 1989}, pages = {2448--2451}, title = {Isolation of three new sesquiterpene lactones from the pericarps of Illicium majus.}, volume = {37}, year = {1989} }