{"created":"2023-05-15T16:41:38.933084+00:00","id":16348,"links":{},"metadata":{"_buckets":{"deposit":"f9347a09-9f86-4449-bc8b-8989c139fd94"},"_deposit":{"created_by":2,"id":"16348","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"16348"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00016348","sets":["14:21"]},"author_link":["61810","61809","61808"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-11-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"27","bibliographicPageEnd":"7000","bibliographicPageStart":"6996","bibliographicVolumeNumber":"54","bibliographic_titles":[{"bibliographic_title":"Electrochimica Acta"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In the present study, the appropriate electrolysis conditions were determined for attaining doped ceria thin films with a high density and adhesion in an aqueous solution containing of Ce3+ and Sm3+ ions. Based on a comparison of the anodic and cathodic polarizations, while the former only induced the deposition of Ce3+, the latter accomplished the simultaneous deposition of Ce and Sm species. Under an applied cathodic bias below the hydrogen evolution potential, the Ce3+ and Sm3+ were reacted with OH- ions generated by the reduction of water molecules, and then were deposited on the electrode as a hydroxide. The hydroxide was subsequently oxidized and dehydrated to form the ceria-based thin layer. The morphologies of the as-deposited films were significantly altered on the basis of the applied potential. Moreover, the addition of acetic acid to the electrolysis bath caused the production of a transparent, dense, and adherent film. The XRD pattern and Raman spectrum of the thin film revealed that the film was crystallized as the fluorite structure without any heat treatment, and Sm3+ is substituted at the Ce4+ site. Moreover, the Sm content in the film could be easily controlled by the metal concentration in the solution.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Electrochimica Acta, 54(27), pp.6996-7000; 2009","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier BV"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.electacta.2009.07.003","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright c 2009 Elsevier Ltd All rights reserved."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00633261","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00134686","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kamada, Kai"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Enomoto, Naoya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hojo, Junichi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-23"}],"displaytype":"detail","filename":"EleAct54_6996.pdf","filesize":[{"value":"352.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"EleAct54_6996.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/16348/files/EleAct54_6996.pdf"},"version_id":"6a5c9c1a-4fc7-4acc-8d54-a431afe69161"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Anti-corrosion","subitem_subject_scheme":"Other"},{"subitem_subject":"Doped ceria","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrochemical coating","subitem_subject_scheme":"Other"},{"subitem_subject":"Soft solution processing","subitem_subject_scheme":"Other"},{"subitem_subject":"Thin film","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Optimization of electrochemical synthesis conditions for dense and doped ceria thin films","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Optimization of electrochemical synthesis conditions for dense and doped ceria thin films"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-10-08"},"publish_date":"2009-10-08","publish_status":"0","recid":"16348","relation_version_is_last":true,"title":["Optimization of electrochemical synthesis conditions for dense and doped ceria thin films"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T19:05:14.669576+00:00"}