{"created":"2023-05-15T16:42:12.214653+00:00","id":17114,"links":{},"metadata":{"_buckets":{"deposit":"9bfbcdaa-2cc4-48ac-b064-69c44dbcf74b"},"_deposit":{"created_by":2,"id":"17114","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"17114"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00017114","sets":["14:21"]},"author_link":["66599","66598"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"746","bibliographicPageStart":"741","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"Electrochemistry Communications"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Phase transition behavior of two-component viologen adsorption layers at a HOPG electrode was described using the results of voltammetric measurements. In the coexistence of heptyl viologen (HV) and its bis-carboxylated derivative in the solution phase, a well-mixed condensed monolayer of the radical cations was formed at any molar fraction. In sharp contrast, the binary system of HV and butyl viologen (BV) exhibited phase separation in the molar fraction range where BV is saturated in the predominantly formed condensed phase of HV. It was, however, found that this separation, being opposed to the prediction based on the adsorption free energy, occurs only when the time period enough for full condensation of HV is not given. The significant features of phase transition of two-component viologen adsorption layers on a HOPG electrode surface were highlighted in comparison with the formation and reductive desorption of the self-assembled monolayers of alkanethiols.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Electrochemistry Communications 9(4), pp.741-746; 2007","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier B.V."}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.elecom.2006.11.007","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright c 2006 Elsevier B.V. All rights reserved."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11324699","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13882481","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tanaka, Yasuhiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sagara, Takamasa"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-23"}],"displaytype":"detail","filename":"Elec_Comm_9_741_2007_NS.pdf","filesize":[{"value":"360.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Elec_Comm_9_741_2007_NS.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/17114/files/Elec_Comm_9_741_2007_NS.pdf"},"version_id":"3d084116-1178-49ec-b842-46d000ab60e9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Viologen","subitem_subject_scheme":"Other"},{"subitem_subject":"HOPG electrode","subitem_subject_scheme":"Other"},{"subitem_subject":"Cyclic voltammetry","subitem_subject_scheme":"Other"},{"subitem_subject":"Phase transition","subitem_subject_scheme":"Other"},{"subitem_subject":"Mixed monolayer","subitem_subject_scheme":"Other"},{"subitem_subject":"Phase separation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Phase transition behavior of two-component viologen adsorption layers on a HOPG electrode surface","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Phase transition behavior of two-component viologen adsorption layers on a HOPG electrode surface"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-03-02"},"publish_date":"2009-03-02","publish_status":"0","recid":"17114","relation_version_is_last":true,"title":["Phase transition behavior of two-component viologen adsorption layers on a HOPG electrode surface"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-17T20:25:11.657759+00:00"}