{"created":"2023-05-15T16:42:39.726803+00:00","id":17754,"links":{},"metadata":{"_buckets":{"deposit":"21451e47-4f65-4927-86e0-02de1dafc633"},"_deposit":{"created_by":2,"id":"17754","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"17754"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00017754","sets":["14:21"]},"author_link":["70147","70149","70148","70146"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-04-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"480","bibliographicPageStart":"475","bibliographicVolumeNumber":"25","bibliographic_titles":[{"bibliographic_title":"Analytical Sciences"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Copper(II) complexes spread on an aqueous solution surface were studied by a polarized total-reflection X-ray absorption fine structure (TR-XAFS) technique. The polarized TR-XAFS spectra at the Cu-K edge for copper(II) porphyrins and copper(II) chlorophyllin in a monolayer were measured in situ at the air-water interface. The polarization dependences of X-ray absorption near-edge structure (XANES) involving a 1s→4pz transition allowed us to estimate the molecular orientation and the local coordination structure around the copper(II) atom in the polarization plane selectively. The extended X-ray absorption fine structure (EXAFS) region of the polarized TR-XAFS spectra for the metal complexes present at the air-water interface was successfully analyzed for the first time. The relative coordination number for the copper center evaluated from the EXAFS analysis indicated larger values in the vertical polarization than in the horizontal one, in agreement with the standing-up molecular orientation at the air-water interface estimated from the XANES region.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Analytical sciences, 25(4), pp.475-480; 2009","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.2116/analsci.25.475","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"2009 (c) The Japan Society for Analytical Chemistry"}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10500785","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09106340","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nagatani, Hirohisa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanida, Hajime"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Watanabe, Iwao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sagara, Takamasa"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-23"}],"displaytype":"detail","filename":"a25_475.pdf","filesize":[{"value":"797.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"a25_475.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/17754/files/a25_475.pdf"},"version_id":"1136a896-7372-4646-9a39-288afa9df236"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"air-water interface","subitem_subject_scheme":"Other"},{"subitem_subject":"porphyrins","subitem_subject_scheme":"Other"},{"subitem_subject":"XAFS","subitem_subject_scheme":"Other"},{"subitem_subject":"EXAFS","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Extended X-ray Absorption Fine Structure of Copper(II) Complexes at the Air-Water Interface by a Polarized Total-Reflection X-ray Absorption Technique","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Extended X-ray Absorption Fine Structure of Copper(II) Complexes at the Air-Water Interface by a Polarized Total-Reflection X-ray Absorption Technique"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-04-16"},"publish_date":"2009-04-16","publish_status":"0","recid":"17754","relation_version_is_last":true,"title":["Extended X-ray Absorption Fine Structure of Copper(II) Complexes at the Air-Water Interface by a Polarized Total-Reflection X-ray Absorption Technique"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T04:24:08.684509+00:00"}