@article{oai:nagasaki-u.repo.nii.ac.jp:00001933, author = {Moon, Sangjoon and Horiuchi, Shinnosuke and Sakuda, Eri and Ito, Akitaka and Arikawa, Yasuhiro and Umakoshi, Keisuke}, journal = {Inorganica Chimica Acta}, month = {Jul}, note = {A butterfly-shaped dinuclear Pt(II) complex having pyridyl-NHC chelate ligands and bridging Me2pz ligands was synthesized. The crystal structure of the Pt2 complex showed short intramolecular Pt?Pt distance (3.129?A) and unique packing structure containing one-dimensional infinite pore that was filled with solvent molecules. The absorbance was proportional to the concentration of Pt2 complex and no significant bands appeared even in high concentration (up to 100?μM). The Pt2 complex showed bluish-green emission (λmax?=?459?nm) in the solid state at 298?K (λex?=?330?nm). TD-DFT calculation revealed that the lowest-energy absorption bands are mainly assigned to the combination of metal-to-ligand charge transfer (MLCT) and ligand-to-ligand charge transfer (LLCT) transitions., Inorganica Chimica Acta, 493, pp.43-48; 2019}, pages = {43--48}, title = {Synthesis and photophysical properties of butterfly-shaped dinuclear Pt(II) complex having NHC-based chelate ligands}, volume = {493}, year = {2019} }