{"created":"2023-05-15T16:30:42.365642+00:00","id":1933,"links":{},"metadata":{"_buckets":{"deposit":"414a7fed-4a72-4d14-9fd4-c26de0a6acd5"},"_deposit":{"created_by":2,"id":"1933","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"1933"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00001933","sets":["14:21"]},"author_link":["8968","8964","8963","8965","8966","8967"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-07-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"48","bibliographicPageStart":"43","bibliographicVolumeNumber":"493","bibliographic_titles":[{"bibliographic_title":"Inorganica Chimica Acta"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A butterfly-shaped dinuclear Pt(II) complex having pyridyl-NHC chelate ligands and bridging Me2pz ligands was synthesized. The crystal structure of the Pt2 complex showed short intramolecular Pt?Pt distance (3.129?A) and unique packing structure containing one-dimensional infinite pore that was filled with solvent molecules. The absorbance was proportional to the concentration of Pt2 complex and no significant bands appeared even in high concentration (up to 100?μM). The Pt2 complex showed bluish-green emission (λmax?=?459?nm) in the solid state at 298?K (λex?=?330?nm). TD-DFT calculation revealed that the lowest-energy absorption bands are mainly assigned to the combination of metal-to-ligand charge transfer (MLCT) and ligand-to-ligand charge transfer (LLCT) transitions.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Inorganica Chimica Acta, 493, pp.43-48; 2019　","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier B.V."}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.ica.2019.04.045","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2019 Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00201693","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Moon, Sangjoon"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Horiuchi, Shinnosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakuda, Eri"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Akitaka"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arikawa, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Umakoshi, Keisuke"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-07-01"}],"displaytype":"detail","filename":"ICA493_43.pdf","filesize":[{"value":"909.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ICA493_43.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/1933/files/ICA493_43.pdf"},"version_id":"bc297311-4851-4033-8d12-aad0f03a57c0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Dinuclear complex","subitem_subject_scheme":"Other"},{"subitem_subject":"Platinum","subitem_subject_scheme":"Other"},{"subitem_subject":"Pyridyl-NHC ligand","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and photophysical properties of butterfly-shaped dinuclear Pt(II) complex having NHC-based chelate ligands","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and photophysical properties of butterfly-shaped dinuclear Pt(II) complex having NHC-based chelate ligands"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-12-18"},"publish_date":"2020-12-18","publish_status":"0","recid":"1933","relation_version_is_last":true,"title":["Synthesis and photophysical properties of butterfly-shaped dinuclear Pt(II) complex having NHC-based chelate ligands"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T23:00:08.149472+00:00"}