{"created":"2023-05-15T16:43:51.814324+00:00","id":19366,"links":{},"metadata":{"_buckets":{"deposit":"79f2c365-6407-48d1-9a18-8383c2ecc9b7"},"_deposit":{"created_by":2,"id":"19366","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"19366"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00019366","sets":["73:74"]},"author_link":["80637","80636","80638","80633","80635","80634"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-08-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"32","bibliographicPageEnd":"7503","bibliographicPageStart":"7498","bibliographicVolumeNumber":"64","bibliographic_titles":[{"bibliographic_title":"Tetrahedron"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Diastereoselective introduction of nucleophiles into L-proline derivatives at the 5-position was achieved with suitable selection of N-protecting group. N-Methoxycarbonylated or benzyloxycarbonylated L-proline derivatives reacted with arene to give cis-arylated products. On the other hand, N-benzoylated L-proline derivative preferentially gave trans-arylated product which could be easily transformed into optically active C2-symmetrical pyrrolidine derivative. Such derivative 5, worked well as an organic activator in the asymmetric reduction of aromatic imines by Cl3SiH.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Tetrahedron, 64(32), pp.7498-7503; 2008","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier BV"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tet.2008.06.004","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2008 Elsevier Ltd All rights reserved."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861787","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404020","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Onomura, Osamu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kirira, Peter G"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Toshimitsu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tsukada, Shinsuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumura, Yoshihiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Demizu, Yosuke"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-23"}],"displaytype":"detail","filename":"Tetra64_7498.pdf","filesize":[{"value":"177.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Tetra64_7498.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/19366/files/Tetra64_7498.pdf"},"version_id":"5883bcf6-a6fd-4abf-ab47-017af919b9ad"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Diastereoselective","subitem_subject_scheme":"Other"},{"subitem_subject":"Organocatalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Asymmetric reduction of imines","subitem_subject_scheme":"Other"},{"subitem_subject":"C2-Symmetrical pyrrolidine","subitem_subject_scheme":"Other"},{"subitem_subject":"Proline derivative","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Diastereoselective arylation of l-proline derivatives at the 5-position","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Diastereoselective arylation of l-proline derivatives at the 5-position"}]},"item_type_id":"2","owner":"2","path":["74"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-07-08"},"publish_date":"2008-07-08","publish_status":"0","recid":"19366","relation_version_is_last":true,"title":["Diastereoselective arylation of l-proline derivatives at the 5-position"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T03:20:22.619680+00:00"}