{"created":"2023-08-03T02:04:38.873959+00:00","id":2000111,"links":{},"metadata":{"_buckets":{"deposit":"50e34397-dba0-46a1-8fad-4ba5246f15e9"},"_deposit":{"created_by":6,"id":"2000111","owner":"6","owners":[6],"owners_ext":{"displayname":"学術コンテンツ担当（図書館員）","username":"libcon_admin"},"pid":{"revision_id":0,"type":"depid","value":"2000111"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:02000111","sets":["14:15:16:1690516757483"]},"author_link":[],"control_number":"2000111","item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Coordination numbers for rare-earths ethylenediaminetetraacetate (REE-EDTA) in crystalline state: a mini-review","subitem_alternative_title_language":"en"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"101","bibliographicPageEnd":"53","bibliographicPageStart":"46","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"長崎大学大学院工学研究科研究報告","bibliographic_titleLang":"ja"},{"bibliographic_title":"Reports of Graduate School of Engineering, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The crystal structures of rare earth elements ethylenediaminetetraacetate (REE-EDTA), including potential applications towards biomedical engineering in MRI, have been briefly reviewed by some researchers. However, there is no systematization of almost all of REE-EDTA complexes; therefore, in the present study, a total of 114 kinds of REE-EDTA (except Sc, Pm, and Tm) were searched in the Cambridge Crystallographic Data Centre (CCDC) and their coordination numbers (C.N.) are summarized. The largest number of registered REE-EDTA is La-EDTA for 22 kinds, followed by 15 Gd-EDTA. The C.N. of each complex ranged from 10 to 9 for light REE (La–Sm) and 10 to 8 for heavy REE (Y and Eu–Lu), suggesting that a decreasing in the C.N. of lanthanoid (Ln)-EDTA is considered to be due to ‘lanthanoid contraction’. The C.N. of Tb-EDTA deviated slightly from the overall decreasing C.N. in Ln-EDTA complexes would be because of a lack of a sufficient number of the studied samples.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学大学院工学研究科研究報告, 53(101), pp.46-53; 2023","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"names":[{"name":"NOGUCHI, Daisuke","nameLang":"en"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学大学院工学研究科研究報告","subitem_publisher_language":"ja"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12601998","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18805574","subitem_source_identifier_type":"ISSN"}]},"item_3_text_62":{"attribute_name":"sortkey","attribute_value_mlt":[{"subitem_text_value":"07"}]},"item_3_text_63":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Reports of Graduate School of Engineering, Nagasaki University"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野口, 大介","creatorNameLang":"ja"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-08-03"}],"filename":"53_101_46.pdf","filesize":[{"value":"638 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://nagasaki-u.repo.nii.ac.jp/record/2000111/files/53_101_46.pdf"},"version_id":"95d4609b-a521-4506-8d29-3a8550ec54fd"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Aminopolycarboxylate","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Chelate","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Complex ion","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Lanthanide","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"希土類-エチレンジアミン四酢酸（REE-EDTA）の結晶状態における配位数：ミニ・レビュー","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"希土類-エチレンジアミン四酢酸（REE-EDTA）の結晶状態における配位数：ミニ・レビュー","subitem_title_language":"ja"}]},"item_type_id":"3","owner":"6","path":["1690516757483"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-08-03"},"publish_date":"2023-08-03","publish_status":"0","recid":"2000111","relation_version_is_last":true,"title":["希土類-エチレンジアミン四酢酸（REE-EDTA）の結晶状態における配位数：ミニ・レビュー"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-08-10T02:45:59.857396+00:00"}