{"created":"2023-10-24T01:17:08.434530+00:00","id":2000256,"links":{},"metadata":{"_buckets":{"deposit":"36fc7101-c791-48f4-b99c-bf08938e7106"},"_deposit":{"created_by":6,"id":"2000256","owner":"6","owners":[6],"pid":{"revision_id":0,"type":"depid","value":"2000256"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:02000256","sets":["14:2044"]},"author_link":[],"control_number":"2000256","item_24_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Addendumof crystal structuralstudyonethylenediaminetetraacetatecomplexes","subitem_alternative_title_language":"en"}]},"item_24_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-10-23","bibliographicIssueDateType":"Issued"},"bibliographic_titles":[{"bibliographic_title":"JXIV","bibliographic_titleLang":"en"}]}]},"item_24_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"エチレンジアミン四酢酸（EDTA）は，ほぼすべての金属イオンとキレートを形成する能力でよく知られた多座配位子である．特にXRD測定法を用いた配位化学の広範な研究により，その構造の多様性が明らかになってきた．ここでは補遺として，ケンブリッジ結晶学データセンター（CCDC）での綿密な調査によって得られたEDTAの塩およびキレートの，金属の種類や配位数を含むいくつかのユニークな構造に関する追加的知見を紹介する．結果として，既存の研究では相互に適切に引用されることなく蓄積されてきたいくつかの報告が見出された．1980年代まではレビューが行われていたものの，包括的な体系化が依然として必要である．従って，次なる努力が新たな知見に結実するだろう．","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"Ethylenediaminetetraacetic acid (EDTA) is a multidentate ligand well-known for its ability to form chelates with nearly all metal ions. Its extensive studiesin coordination chemistryusingspecifi-cally XRD measurementshaveresulted in their structural variability. Here, as an addendum, I present additional findings on some unique structures of EDTA salts and chelates, including their metal types and coordination numbers, obtained through meticulous investigation at the Cambridge Crystallographic Data Centre (CCDC). It was revealed that theexisting research has uncovered somereports that have accumulated without being cited properlywith each other.Although itwas reviewed up until the 1980s, a comprehensive systematizationis still required. Thus, followingendeavorwilllead to new knowledge.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_24_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"JXIV, doi.org/10.51094/jxiv.531; 2023","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_24_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"names":[{"name":"NOGUCHI, Daisuke","nameLang":"en"}]}]},"item_24_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"科学技術振興機構","subitem_publisher_language":"ja"}]},"item_24_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.51094/jxiv.531","subitem_relation_type_select":"DOI"}}]},"item_24_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"ⓒ 2023 野口, 大介. Creative Commons License.この作品は、Creative Commons Attribution 4.0 International Licenseの下でライセンスされています。","subitem_rights_language":"ja"}]},"item_24_text_62":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Japan Science and Technology Agency"}]},"item_24_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野口, 大介","creatorNameLang":"ja"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-10-24"}],"filename":"JXIV_531.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://nagasaki-u.repo.nii.ac.jp/record/2000256/files/JXIV_531.pdf"},"version_id":"a0ad8d38-0452-4199-9370-cb30d4b44250"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Aminopolycarboxylic acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"CCDC","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Coordinationnumber","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"EDTAChelate","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"エチレンジアミン四酢酸錯体に関する結晶構造研究の補遺","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"エチレンジアミン四酢酸錯体に関する結晶構造研究の補遺","subitem_title_language":"ja"}]},"item_type_id":"24","owner":"6","path":["2044"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-10-24"},"publish_date":"2023-10-24","publish_status":"0","recid":"2000256","relation_version_is_last":true,"title":["エチレンジアミン四酢酸錯体に関する結晶構造研究の補遺"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-10-24T02:17:01.648743+00:00"}