@article{oai:nagasaki-u.repo.nii.ac.jp:02000815, author = {Hanazawa, Natsumi and Kuriyama, Masami and Yamamoto, Kosuke and Onomura, Osamu}, issue = {8}, journal = {Molecules}, month = {Apr}, note = {An oxidative C–C bond cleavage of tert-cycloalkanols with tetramethylammonium hypochlorite (TMAOCl) has been developed. TMAOCl is easy to prepare from tetramethylammonium hydroxide, and the combination of TMAOCl and AcOH effectively promoted the C–C bond cleavage in a two-phase system without additional phase-transfer reagents. Unstrained tert-cycloalkanols were transformed into ω-chloroalkyl aryl ketones in moderate to excellent yields under metal-free and mild reaction conditions., Molecules, 29(8), art. no. 1874; 2024}, title = {Synthesis of ω-Chloroalkyl Aryl Ketones via C–C Bond Cleavage of tert-Cycloalkanols with Tetramethylammonium Hypochlorite}, volume = {29}, year = {2024} }