{"created":"2023-05-15T16:44:37.980440+00:00","id":20360,"links":{},"metadata":{"_buckets":{"deposit":"db89245a-51ad-4687-b27b-8878e53a1477"},"_deposit":{"created_by":2,"id":"20360","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"20360"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00020360","sets":["73:74"]},"author_link":["86175","86174","86173","86172"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicPageEnd":"3942","bibliographicPageStart":"3935","bibliographicVolumeNumber":"64","bibliographic_titles":[{"bibliographic_title":"Tetrahedron"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"N-Protecting groups of α-substituted cyclic amines strongly affected the regioselectivity in electrochemical methoxylation of these compounds. Namely, N-acyl derivatives were transformed into α′-methoxylated compounds, while N-cyano derivatives changed into α-methoxylated derivatives. Furthermore, Lewis acid catalyzed nucleophilic substitution of the α-methoxylated compounds protected with cyano group afforded α,α-disubstituted cyclic amines.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Tetrahedron, 64(18), pp.3935-3942; 2008","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tet.2008.02.060","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright c 2008 Elsevier Ltd All rights reserved."}]},"item_2_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861787","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404020","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Libendi, Samuel S."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Demizu, Yosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumura, Yoshihiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Onomura, Osamu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-23"}],"displaytype":"detail","filename":"Tetra64_3935.pdf","filesize":[{"value":"247.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Tetra64_3935.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/20360/files/Tetra64_3935.pdf"},"version_id":"a8404411-95cc-41c8-89d1-af7d361e8b49"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Cyclic amines","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrochemical oxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"Regioselective","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"High regioselectivity in electrochemical α-methoxylation of N-protected cyclic amines","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"High regioselectivity in electrochemical α-methoxylation of N-protected cyclic amines"}]},"item_type_id":"2","owner":"2","path":["74"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-04-03"},"publish_date":"2008-04-03","publish_status":"0","recid":"20360","relation_version_is_last":true,"title":["High regioselectivity in electrochemical α-methoxylation of N-protected cyclic amines"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T19:24:58.017326+00:00"}