{"created":"2023-05-15T16:30:51.733672+00:00","id":2147,"links":{},"metadata":{"_buckets":{"deposit":"31eb36ea-f70e-4b91-8856-4b9dc5b16d8c"},"_deposit":{"created_by":2,"id":"2147","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"2147"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00002147","sets":["14:21"]},"author_link":["9952","9954","9951","9953"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-10-19","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"42","bibliographicPageEnd":"4745","bibliographicPageStart":"4742","bibliographicVolumeNumber":"57","bibliographic_titles":[{"bibliographic_title":"Tetrahedron Letters"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"To develop reaction systems of chemical conversion of biomass, fructose was heated in an aqueous medium under pressurized CO2, which caused in situ generation of carbonic acid. It gave 5-hydroxymethyl-2-furfural (HMF) as a dehydration product in good yields. The maximum yield of HMF was 92% in the reaction at 90 °C under 7.0 MPa of CO2 for 168 h. The reaction proceeded in the absence of any other reagents such as non-volatile acids, organic solvents, inorganic, and organic salts. It means green, environmental-friendly, and efficient process was achieved for production of HMF.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Tetrahedron Letters, 57(42), pp.4742-4745; 2016","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Ltd."}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tetlet.2016.09.036","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2016 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404039","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Motokucho, Suguru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Morikawa, Hiroshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakatani, Hisayuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Noordover, Bart A.J."}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"TetLet57_4742.pdf","filesize":[{"value":"263.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TetLet57_4742.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/2147/files/TetLet57_4742.pdf"},"version_id":"df93c967-ff93-45e7-85f6-15cde317598e"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Biomass","subitem_subject_scheme":"Other"},{"subitem_subject":"Carbonic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"CO2","subitem_subject_scheme":"Other"},{"subitem_subject":"Dehydration reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"Fructose","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-10-20"},"publish_date":"2018-10-20","publish_status":"0","recid":"2147","relation_version_is_last":true,"title":["Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T03:52:05.063781+00:00"}