{"created":"2023-05-15T16:45:56.976538+00:00","id":22104,"links":{},"metadata":{"_buckets":{"deposit":"722c74e7-6e1a-4dfb-a426-a6e93298816c"},"_deposit":{"created_by":2,"id":"22104","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"22104"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00022104","sets":["14:15:1180:1566"]},"author_link":["94379","94376","94377","94375","94372","94374","94378","94373"],"item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Molecular Release Behavior of Core-shell Type Hyperbranched Polymer"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"69","bibliographicPageEnd":"37","bibliographicPageStart":"33","bibliographicVolumeNumber":"37","bibliographic_titles":[{"bibliographic_title":"長崎大学工学部研究報告"},{"bibliographic_title":"Reports of the Faculty of Engineering, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Polyglycerol-polyethylene imine (PGL-PEI) was synthesized from glycidol and polyethylene imine (PEI) as a core-shell type hyperbranched polymer.  PGL-PEI was characterized by 1H, 13C nuclear magnetic resonance (1H, 13C-NMR) spectroscopy, gel permeation chromatography (GPC). Using benzylcinamate (BC) as a guest molecule, release behavior of PGL-PEI was investigated by ultraviolet visible (UV-vis) spectroscopy.  The 13C-NMR spectrum is complicated and suggests a highly branched structure for the PGL-PEI.  And GPC profile of PGL-PEI gave a unimodal profile.  These results suggest that the PGL-PEI was successfully prepared by the monomer slow addition method.  To confirm the PGL-PEI release behavior by UV-vis measurement, the PGL-PEI after loading BC was dissolved in water at the pH 10.01.  For UV-vis spectra of B-band of BC decreased with pH decreasing.  We demonstrated the PGL-PEI successfully shows release behavior.","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学工学部研究報告 Vol.37(69) p.33-37, 2007","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"94376","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Motokucho, Suguru"}]},{"nameIdentifiers":[{"nameIdentifier":"94377","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Inaba, Takeshi"}]},{"nameIdentifiers":[{"nameIdentifier":"94378","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kojio, Ken"}]},{"nameIdentifiers":[{"nameIdentifier":"94379","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Furukawa, Mutsuhisa"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学工学部"}]},"item_3_relation_42":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.lb.nagasaki-u.ac.jp/reports/kougaku/preview.php?id=52"}]}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12080680","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_8":{"attribute_name":"EISSN","attribute_value_mlt":[{"subitem_source_identifier":"1880-5574","subitem_source_identifier_type":"ISSN"}]},"item_3_text_62":{"attribute_name":"sortkey","attribute_value_mlt":[{"subitem_text_value":"P00033-P00037"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"本九町, 卓"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"稲葉, 健"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小椎尾, 謙"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"古川, 睦久"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-24"}],"displaytype":"detail","filename":"37_69_06.pdf","filesize":[{"value":"469.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"37_69_06.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/22104/files/37_69_06.pdf"},"version_id":"9a56a5cc-5c21-498e-9efb-edbe5019318e"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"hyperbranched polymer","subitem_subject_scheme":"Other"},{"subitem_subject":"stimuli-responsible polymer","subitem_subject_scheme":"Other"},{"subitem_subject":"capture-release behavior","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"コアシェル型多分岐性高分子の分子放出挙動","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"コアシェル型多分岐性高分子の分子放出挙動"}]},"item_type_id":"3","owner":"2","path":["1566"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-12-03"},"publish_date":"2007-12-03","publish_status":"0","recid":"22104","relation_version_is_last":true,"title":["コアシェル型多分岐性高分子の分子放出挙動"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T01:27:43.305242+00:00"}