{"created":"2023-05-15T16:31:15.290184+00:00","id":2617,"links":{},"metadata":{"_buckets":{"deposit":"00a918aa-b963-4c88-b674-a1e0ae50bfff"},"_deposit":{"created_by":2,"id":"2617","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"2617"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00002617","sets":["73:74"]},"author_link":["12061","12059","12060","12062"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-09-18","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"39","bibliographicPageEnd":"11859","bibliographicPageStart":"11855","bibliographicVolumeNumber":"56","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Goupiolones?A and B are unique phenolic compounds with significant DNA-damaging activity. In this study, the structure of goupiolone?B was revised on the basis of DFT calculations of the 13C?NMR chemical shifts and biosynthetic considerations. The dibenzobicyclo[3.2.2]nonane skeleton of the revised structure suggested that goupiolone?B was produced by oxidative coupling between catechol and goupiolone?A, which was strongly supported by biomimetic synthesis. Furthermore, racemization of goupiolone?B was observed during the attempted resolution of its racemic mixture. A plausible racemization mechanism involving α-ketol rearrangement is proposed.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Angewandte Chemie International Edition, 56(39), pp.11855-11859; 2017","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-VCH Verlag GmbH & Co. KGaA"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/anie.201706532","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim"},{"subitem_rights":"This is the accepted version of the following article: Angewandte Chemie - International Edition, 56(39), pp.11855-11859; 2017, which has been published in final form at http://dx.doi.org/10.1002/anie.201706532 This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy http://olabout.wiley.com/WileyCDA/Section/id-820227.html"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"14337851","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matsuo, Yosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshida, Ayane"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Saito, Yoshinori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Takashi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"ACIE56_11855.pdf","filesize":[{"value":"243.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACIE56_11855.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/2617/files/ACIE56_11855.pdf"},"version_id":"0b1e1db3-5789-40bf-91cb-d722d241d03c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"natural products","subitem_subject_scheme":"Other"},{"subitem_subject":"biomimetic synthesis","subitem_subject_scheme":"Other"},{"subitem_subject":"structure elucidation","subitem_subject_scheme":"Other"},{"subitem_subject":"oxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"rearrangement","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structural Revision and Biomimetic Synthesis of Goupiolone?B","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structural Revision and Biomimetic Synthesis of Goupiolone?B"}]},"item_type_id":"2","owner":"2","path":["74"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-09-18"},"publish_date":"2018-09-18","publish_status":"0","recid":"2617","relation_version_is_last":true,"title":["Structural Revision and Biomimetic Synthesis of Goupiolone?B"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T03:43:59.148592+00:00"}