{"created":"2023-05-15T16:49:03.131738+00:00","id":26328,"links":{},"metadata":{"_buckets":{"deposit":"f226d8eb-c824-4fad-bf00-8c95a5fa992d"},"_deposit":{"created_by":6,"id":"26328","owners":[6],"pid":{"revision_id":0,"type":"depid","value":"26328"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00026328","sets":["14:21"]},"author_link":["117211","117210","117209","117208","117207","117212"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-02-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"6267","bibliographicPageStart":"6259","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"RSC Advances"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Novel bis(dipyrrinato)zinc(ii) derivatives having 4-[bis(2,4,6-trimethylphenyl)boryl]phenyl (ZnBph) or\n 4-[bis(2,4,6-trimethylphenyl)boryl]-2,3,5,6-tetramethylphenyl groups (ZnBdu) at the 5-position of the dipyrrinato ligands were designed and synthesized.InZnBphwith the smaller dipyrrinate-arylene and arylene-dimesitylboryl dihedral angles, an intramolecular charge transfer arising from the presence of the vacant p orbital on the boron atom participates in the ππ* excited state in character in contrast to the pure ππ* excited state ofZnBdu. The synergistic ππ*/ILCT excited state was weakly fluorescent, and the fluorescence was enhanced upon binding of fluoride to the boron atom.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"RSC Advances, 11(11), pp.6259-6267; 2021","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/D0RA09029H","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© The Royal Society of Chemistry 2021. Open Access Article. Published on 03 February 2021. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence."}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2046-2069","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takaki, Koyo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakuda, Eri"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ito, Akitaka"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Horiuchi, Shinnosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arikawa, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Umakoshi, Keisuke"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-03-02"}],"displaytype":"detail","filename":"RSCAd11_6259.pdf","filesize":[{"value":"870.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"RSCAd11_6259.pdf ","url":"https://nagasaki-u.repo.nii.ac.jp/record/26328/files/RSCAd11_6259.pdf"},"version_id":"d61d0430-3dcb-414c-a78a-53cef013ec14"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Bridging-arylene effects on spectroscopic and photophysical properties of arylborane–dipyrrinato zinc(ii) complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Bridging-arylene effects on spectroscopic and photophysical properties of arylborane–dipyrrinato zinc(ii) complexes"}]},"item_type_id":"2","owner":"6","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-03-02"},"publish_date":"2021-03-02","publish_status":"0","recid":"26328","relation_version_is_last":true,"title":["Bridging-arylene effects on spectroscopic and photophysical properties of arylborane–dipyrrinato zinc(ii) complexes"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-05-15T20:28:46.274381+00:00"}