{"created":"2023-05-15T16:49:28.838351+00:00","id":26953,"links":{},"metadata":{"_buckets":{"deposit":"9ef8ef21-73cf-46d6-96cc-45f7145d513e"},"_deposit":{"created_by":6,"id":"26953","owners":[6],"pid":{"revision_id":0,"type":"depid","value":"26953"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00026953","sets":["10:11"]},"author_link":["119995","119996","119997","119998"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-10-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"1467","bibliographicPageStart":"1465","bibliographicVolumeNumber":"37","bibliographic_titles":[{"bibliographic_title":"Analytical Sciences"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Although benzofuran-2-boronic acid hardly emits fluorescence, it can be rapidly converted to a highly fluorescent benzofuran dimer after mixing with a palladium catalyst and amine. We found that a fluorescence enhancement accompanying dimerization was quantitatively promoted upon increasing the concentration of amine. In the present study, we developed a simple fluorescence assay for amines based on the promotive effect. As the result of a fluorescence measurement of the reaction mixture of 19 kinds of typical amines, it was found that tertiary amines including triethylamine (TEA) provided a significant fluorescence enhancement. Finally, the fluorogenic reaction could be applied to develop a high-throughput fluorescent microplate assay for TEA with the limit of detection (blank + 3SD) of 0.091 μM.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Analytical Sciences, 37(10), pp. 1465-1467; 2021","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.2116/analsci.21N007","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2021 by The Japan Society for Analytical Chemistry"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0910-6340","subitem_source_identifier_type":"ISSN"}]},"item_2_source_id_8":{"attribute_name":"EISSN","attribute_value_mlt":[{"subitem_source_identifier":"1348-2246","subitem_source_identifier_type":"ISSN"}]},"item_2_text_62":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"The Japan Society for Analytical Chemistry"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"TANGE, Akari"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"HIGASHI, Azumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"KISHIKAWA, Naoya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"KURODA, Naotaka"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-12-21"}],"displaytype":"detail","filename":"AnaSci37_1465.pdf","filesize":[{"value":"122.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AnaSci37_1465.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/26953/files/AnaSci37_1465.pdf"},"version_id":"9129f0a3-78da-4b7d-b08e-ad98e40cd73d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Triethylamine","subitem_subject_scheme":"Other"},{"subitem_subject":"fluorescence assay","subitem_subject_scheme":"Other"},{"subitem_subject":"benzofuran-2-boronic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"fluorogenic dimerization reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"palladium","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Simple Fluorescence Assay for Triethylamine Based on the Palladium Catalytic Dimerization of Benzofuran-2-boronic Acid","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Simple Fluorescence Assay for Triethylamine Based on the Palladium Catalytic Dimerization of Benzofuran-2-boronic Acid"}]},"item_type_id":"2","owner":"6","path":["11"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-12-21"},"publish_date":"2021-12-21","publish_status":"0","recid":"26953","relation_version_is_last":true,"title":["Simple Fluorescence Assay for Triethylamine Based on the Palladium Catalytic Dimerization of Benzofuran-2-boronic Acid"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-05-15T20:05:00.176051+00:00"}