{"created":"2023-05-15T16:49:52.874688+00:00","id":27518,"links":{},"metadata":{"_buckets":{"deposit":"9da7c130-a565-4e18-a7a4-d6e72989ae90"},"_deposit":{"created_by":6,"id":"27518","owners":[6],"pid":{"revision_id":0,"type":"depid","value":"27518"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00027518","sets":["14:15:16:2036"]},"author_link":["122338","122337"],"item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"EDTA complexes of aluminum and other earth metals with some unique crystal structures: A brief overview"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"99","bibliographicPageEnd":"37","bibliographicPageStart":"30","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"長崎大学大学院工学研究科研究報告"},{"bibliographic_title":"Reports of Graduate School of Engineering, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Aluminum, gallium, indium, and thallium, forming trivalent cations, are r eferred to as earth metals; only Tl also has stable monovalent one. The complexes of Al, for instance, have studied to elucidate industrial use and toxic effects in materials engineering and environmental science. Here, I briefly overview the reported crystal structures of earth metal-complexes chelated by EDTA (ethylenediaminetetraacetic acid) to deepen our knowledge and apply for further research. Bibliographic survey has revealed that 6 of Al-, 14 of Ga-, 6 of In-, and 2 of Tl(III)-EDTA were reported for the crystal structures, showing that the coordination numbers of Al3+ and Ga3+ are 6, In3+ and Tl3+ are 7 in the crystal state. The denticity of EDTA anions are not only hexadentate but also pentadentate (the fourth carboxy group is uncoordinated) in six complexes. A dinuclear Al2-EDTA complex, with two Al3+ bridged by (μ-OH-)2, has a unique cis-conformation of ethylenediamine moiety; it was appeared to have few other analogues.","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学大学院工学研究科研究報告, 52(99), pp.30-37; 2022","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"122338","nameIdentifierScheme":"WEKO"}],"names":[{"name":"NOGUCHI, Daisuke"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学大学院工学研究科"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12601998","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18805574","subitem_source_identifier_type":"ISSN"}]},"item_3_text_62":{"attribute_name":"sortkey","attribute_value_mlt":[{"subitem_text_value":"05"}]},"item_3_text_63":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Engineering, Nagasaki University"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野口, 大介"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-08-01"}],"displaytype":"detail","filename":"52_99_30.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"52_99_30.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/27518/files/52_99_30.pdf"},"version_id":"25a05d04-be07-4b52-b391-db92bf4439a9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Chelate","subitem_subject_scheme":"Other"},{"subitem_subject":"Coordination chemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"Gallium","subitem_subject_scheme":"Other"},{"subitem_subject":"Indium","subitem_subject_scheme":"Other"},{"subitem_subject":"Polyaminocarboxylate","subitem_subject_scheme":"Other"},{"subitem_subject":"Thallium","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"一部にユニークな結晶構造を有するアルミニウムをはじめとする土類金属-EDTA 錯体（概論）","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"一部にユニークな結晶構造を有するアルミニウムをはじめとする土類金属-EDTA 錯体（概論）"}]},"item_type_id":"3","owner":"6","path":["2036"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-08-01"},"publish_date":"2022-08-01","publish_status":"0","recid":"27518","relation_version_is_last":true,"title":["一部にユニークな結晶構造を有するアルミニウムをはじめとする土類金属-EDTA 錯体（概論）"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-05-15T19:40:32.354515+00:00"}