{"created":"2023-05-15T16:49:58.229783+00:00","id":27642,"links":{},"metadata":{"_buckets":{"deposit":"0c50fb18-9623-4a6f-9ee8-07d2926e284f"},"_deposit":{"created_by":6,"id":"27642","owners":[6],"pid":{"revision_id":0,"type":"depid","value":"27642"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00027642","sets":["10:11"]},"author_link":["122921","122920","122918","122922","122919"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-08-22","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"1069","bibliographicPageStart":"1062","bibliographicVolumeNumber":"18","bibliographic_titles":[{"bibliographic_title":"Beilstein Journal of Organic Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Electrochemical pinacol coupling of carbonyl compounds in an undivided cell with a sacrificial anode would be a promising approach toward synthetically valuable vic-1,2-diol scaffolds without using low-valent metal reductants. However, sacrificial anodes produce an equimolar amount of metal waste, which may be a major issue in terms of sustainable chemistry. Herein, we report a sacrificial anode-free electrochemical protocol for the synthesis of pinacol-type vic-1,2-diols from sec-alcohols, namely benzyl alcohol derivatives and ethyl lactate. The corresponding vic-1,2-diols are obtained in moderate to good yields, and good to high levels of stereoselectivity are observed for sec-benzyl alcohol derivatives. The present transformations smoothly proceed in a simple undivided cell under constant current conditions without the use of external chemical oxidants/reductants, and transitionmetal catalysts.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Beilstein Journal of Organic Chemistry, 18, pp.1062-1069; 2022　","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Beilstein-Institut Zur Forderung der Chemischen Wissenschaften"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3762/bjoc.18.108","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2022 Yamamoto et al.; licensee Beilstein-Institut. License and terms: This is an open access article licensed under the terms of the Beilstein-Institut Open Access License Agreement (https://www.beilstein-journals.org/bjoc/terms), which is identical to the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0). The reuse of material under this license requires that the author(s), source and license are credited. Third-party material in this article could be subject to other licenses (typically indicated in the credit line), and in this case, users are required to obtain permission from the license holder to reuse the material."}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1860-5397","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamoto, Kosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arita, Kazuhisa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shiota, Masashi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kuriyama, Masami"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Onomura, Osamu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-10-07"}],"displaytype":"detail","filename":"BJOC18_1062.pdf","filesize":[{"value":"460.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"BJOC18_1062.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/27642/files/BJOC18_1062.pdf"},"version_id":"35d9b495-236b-4cc2-801c-dc03d055dc23"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"alcohols","subitem_subject_scheme":"Other"},{"subitem_subject":"dimerization","subitem_subject_scheme":"Other"},{"subitem_subject":"electrooxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"electroreduction","subitem_subject_scheme":"Other"},{"subitem_subject":"paired electrolysis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electrochemical formal homocoupling of sec-alcohols","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electrochemical formal homocoupling of sec-alcohols"}]},"item_type_id":"2","owner":"6","path":["11"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-10-07"},"publish_date":"2022-10-07","publish_status":"0","recid":"27642","relation_version_is_last":true,"title":["Electrochemical formal homocoupling of sec-alcohols"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-05-15T19:35:19.495907+00:00"}