{"created":"2023-05-15T16:50:08.884297+00:00","id":27886,"links":{},"metadata":{"_buckets":{"deposit":"c22c1a18-61d1-4041-bfca-dbe8de6b4853"},"_deposit":{"created_by":6,"id":"27886","owners":[6],"pid":{"revision_id":0,"type":"depid","value":"27886"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00027886","sets":["14:15:16:2048"]},"author_link":["124302","124301"],"item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Comparative structural analysis of late first-row transition metal-EDTA chelates"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"100","bibliographicPageEnd":"78","bibliographicPageStart":"71","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"長崎大学大学院工学研究科研究報告"},{"bibliographic_title":"Reports of Graduate School of Engineering, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Based on the data available in Cambridge Crystallographic Data Centre (CCDC), the crystal structures of late first-row transition metal-complexes chelated by ethylenediaminetetraacetic acid (EDTA) are overviewed. Herein, it is summarized that the crystal structures of 17 of FeIII-EDTA, 6 of FeII-EDTA, 21 of CoIII-EDTA, 14 of CoII-EDTA, 13 of Ni-EDTA, 22 of Cu-EDTA, and 7 of Zn-EDTA complexes (total 100 kinds) have coordination numbers (CN) ranging from 5 to 7, most have CN = 6(70/100), and the denticities of these chelates are tetra-, penta-, and hexadentate. In analytical chemistry, typically learned complexes of hexadentate and CN = 6 are found to be only 33 cases (ca. 33%), not major species in the late first-row transition metal-EDTA complexes, following up on the former review.","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学大学院工学研究科研究報告, 53(100), pp.71-78; 2023","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"124302","nameIdentifierScheme":"WEKO"}],"names":[{"name":"NOGUCHI, Daisuke"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学大学院工学研究科"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12601998","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18805574","subitem_source_identifier_type":"ISSN"}]},"item_3_text_62":{"attribute_name":"sortkey","attribute_value_mlt":[{"subitem_text_value":"10"}]},"item_3_text_63":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Engineering, Nagasaki University"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野口, 大介"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-01-31"}],"displaytype":"detail","filename":"53_100_71.pdf","filesize":[{"value":"589.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"53_100_71.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/27886/files/53_100_71.pdf"},"version_id":"c49722b5-56be-4bcb-981c-21ca30936ea4"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"D-block","subitem_subject_scheme":"Other"},{"subitem_subject":"Denticity","subitem_subject_scheme":"Other"},{"subitem_subject":"Sexidentate ligand","subitem_subject_scheme":"Other"},{"subitem_subject":"Transition elements","subitem_subject_scheme":"Other"},{"subitem_subject":"X-ray crystallography","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"後期第一系列遷移金属-EDTA キレートの比較構造解析","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"後期第一系列遷移金属-EDTA キレートの比較構造解析"}]},"item_type_id":"3","owner":"6","path":["2048"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-01-31"},"publish_date":"2023-01-31","publish_status":"0","recid":"27886","relation_version_is_last":true,"title":["後期第一系列遷移金属-EDTA キレートの比較構造解析"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-05-15T18:15:25.047502+00:00"}