{"created":"2023-05-15T16:50:08.971016+00:00","id":27888,"links":{},"metadata":{"_buckets":{"deposit":"ed1d6da6-67ca-4f07-b37f-31af35b3d43a"},"_deposit":{"created_by":6,"id":"27888","owners":[6],"pid":{"revision_id":0,"type":"depid","value":"27888"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00027888","sets":["14:15:16:2048"]},"author_link":["124306","124305"],"item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Intramolecular and intermolecular hydrogen bonds in non-chelation ethylenediaminetetraacetic acid (EDTA) and its salts"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"100","bibliographicPageEnd":"94","bibliographicPageStart":"87","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"長崎大学大学院工学研究科研究報告"},{"bibliographic_title":"Reports of Graduate School of Engineering, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Ethylenediaminetetraacetic acid (EDTA), non-chelating conformational salts, and chelates of alkaline earth metals thereof have recently been reported to be room temperature phosphorescence (RTP)-emissive. The origin of RTP was identified as through-space conjugation by hydrogen bonding. Although crystal structures of other non-chelating EDTA and its salts have been previously reported, RTP-emissive or not are unknown. Therefore, in the present study, I investigate the intra- and inter- molecular hydrogen bonding distances in the crystals of 25 non-chelating EDTA and their salts using Cambridge Structural Database (CSD). Integrating the RTP ability with the reported crystal structures of EDTA and salts thereof including metal-EDTA chelates would be an intriguing research in the future.","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学大学院工学研究科研究報告, 53(100), pp.87-94; 2023","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"124306","nameIdentifierScheme":"WEKO"}],"names":[{"name":"NOGUCHI, Daisuke"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学大学院工学研究科"}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12601998","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18805574","subitem_source_identifier_type":"ISSN"}]},"item_3_text_62":{"attribute_name":"sortkey","attribute_value_mlt":[{"subitem_text_value":"12"}]},"item_3_text_63":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Engineering, Nagasaki University"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野口, 大介"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-01-31"}],"displaytype":"detail","filename":"53_100_87.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"53_100_87.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/27888/files/53_100_87.pdf"},"version_id":"66868a78-a7da-49b4-8deb-a9869741730c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Complex ion","subitem_subject_scheme":"Other"},{"subitem_subject":"Ligand","subitem_subject_scheme":"Other"},{"subitem_subject":"Room-temperature phosphorescence","subitem_subject_scheme":"Other"},{"subitem_subject":"X-ray Crystallography","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"非キレート性エチレンジアミン四酢酸（EDTA）とその塩における分子内・分子間水素結合","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"非キレート性エチレンジアミン四酢酸（EDTA）とその塩における分子内・分子間水素結合"}]},"item_type_id":"3","owner":"6","path":["2048"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-01-31"},"publish_date":"2023-01-31","publish_status":"0","recid":"27888","relation_version_is_last":true,"title":["非キレート性エチレンジアミン四酢酸（EDTA）とその塩における分子内・分子間水素結合"],"weko_creator_id":"6","weko_shared_id":-1},"updated":"2023-05-15T18:15:20.068385+00:00"}