{"created":"2023-05-15T16:32:04.029330+00:00","id":3741,"links":{},"metadata":{"_buckets":{"deposit":"3b0ba009-8197-4181-9132-89163da0e5e5"},"_deposit":{"created_by":2,"id":"3741","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"3741"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00003741","sets":["14:21"]},"author_link":["15271","15270","15273","15272"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-02-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"72","bibliographicPageStart":"67","bibliographicVolumeNumber":"803","bibliographic_titles":[{"bibliographic_title":"Journal of Organometallic Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A silver complex bearing 2,6-bis(3-tert-butylimidazol-2-ylidene)pyridine (CNC) ligands was easily prepared from the reaction of the CNC ligand precursor with Ag2O. The CNC ligand contains relatively bulky substituents, tert-butyl, on nitrogen atoms. Use of the silver complex as a carbene transfer reagent gave rise to a copper and a gold complex, completing a series of coinage metal complexes [M2(CNC)2](BF4)2 (M = Cu, Ag, Au). In all the coinage metal complexes, the X-ray crystallographic analyses showed that the two CNC ligand strands are intertwined each other and surround the metal ions in a double helical fashion. Moreover, the carbene transfer reactions afforded a monomeric palladium complex [Pd(CNC)Cl]BF4 and a CNC-bridged dipalladium complex [{Pd(η3-C3H5)Cl}2(μ-CNC)]. Facile chloride ligand abstraction from the dipalladium complex yielded a chlorido-bridged dipalladium complex [{Pd(η3-C3H5)}2(μ-CNC)(μ-Cl)]BF4.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Journal of Organometallic Chemistry, 803, pp.67-72; 2016","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jorganchem.2015.12.006","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2015 Elsevier B.V. All rights reserved."},{"subitem_rights":"This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022328X","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakamura, Takuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ogushi, Shinji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arikawa, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Umakoshi, Keisuke"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"JOC803_67.pdf","filesize":[{"value":"385.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JOC803_67.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/3741/files/JOC803_67.pdf"},"version_id":"9b056738-900b-45a1-af63-7b124574cb1b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Bis(carbene) ligand","subitem_subject_scheme":"Other"},{"subitem_subject":"tert-Butyl substituents","subitem_subject_scheme":"Other"},{"subitem_subject":"Carbene transfer","subitem_subject_scheme":"Other"},{"subitem_subject":"Coinage metal complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"Palladium","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Preparations of a series of coinage metal complexes with pyridine-based bis(N-heterocyclic carbene) ligands including transmetalation to palladium complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Preparations of a series of coinage metal complexes with pyridine-based bis(N-heterocyclic carbene) ligands including transmetalation to palladium complexes"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-02-02"},"publish_date":"2018-02-02","publish_status":"0","recid":"3741","relation_version_is_last":true,"title":["Preparations of a series of coinage metal complexes with pyridine-based bis(N-heterocyclic carbene) ligands including transmetalation to palladium complexes"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T03:29:17.906073+00:00"}