{"created":"2023-05-15T16:32:29.341140+00:00","id":4352,"links":{},"metadata":{"_buckets":{"deposit":"200fecf7-8adb-4684-8f98-4509b5ba53fb"},"_deposit":{"created_by":2,"id":"4352","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"4352"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00004352","sets":["73:74"]},"author_link":["17374","17375","17379","17378","17380","17376","17381","17373","17377","17372"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-06-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"23","bibliographicPageEnd":"3914","bibliographicPageStart":"3909","bibliographicVolumeNumber":"71","bibliographic_titles":[{"bibliographic_title":"Tetrahedron"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Chiral cyclic α,α-disubstituted α-amino acids with four chiral centers at their acetal moieties were synthesized. An X-ray crystallographic analysis of homo-chiral tripeptide with (2R,3R)-butane-2,3-diol acetal moieties revealed that the tripeptide formed both (P) and (M) helical structures, and all peptide main-chain N(i)-H were intramolecularly hydrogen-bonded with the side-chain acetal -O- of the same amino acid residues (i). The effect of the four chiral centers in the amino acid residue on the peptide backbone helical-screw control was very weak.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Tetrahedron, 71(23), pp.3909-3914; 2015","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Ltd"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tet.2015.04.031","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2015 Elsevier Ltd. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404020","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tanda, Kazuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Eto, Ryo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kato, Kazuya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Oba, Makoto"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ueda, Atsushi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Suemune, Hiroshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Doi, Mitsunobu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Demizu, Yosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kurihara, Masaaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Masakazu"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"Supple.pdf","filesize":[{"value":"487.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Supple.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/4352/files/Supple.pdf"},"version_id":"f2fd10f5-db6c-415c-8eb3-cea26ae8941c"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"Tetra71_3909.pdf","filesize":[{"value":"334.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Tetra71_3909.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/4352/files/Tetra71_3909.pdf"},"version_id":"720af494-1ce9-4a34-ae69-76871ee7b59c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Conformation","subitem_subject_scheme":"Other"},{"subitem_subject":"Foldamer","subitem_subject_scheme":"Other"},{"subitem_subject":"Helix","subitem_subject_scheme":"Other"},{"subitem_subject":"Peptides","subitem_subject_scheme":"Other"},{"subitem_subject":"α,α-disubstituted α-amino acid","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Peptide foldamers composed of six-membered ring α,α-disubstituted α-amino acids with two changeable chiral acetal moieties","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Peptide foldamers composed of six-membered ring α,α-disubstituted α-amino acids with two changeable chiral acetal moieties"}]},"item_type_id":"2","owner":"2","path":["74"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-06-11"},"publish_date":"2017-06-11","publish_status":"0","recid":"4352","relation_version_is_last":true,"title":["Peptide foldamers composed of six-membered ring α,α-disubstituted α-amino acids with two changeable chiral acetal moieties"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T03:22:46.331246+00:00"}