{"created":"2023-05-15T16:32:58.812665+00:00","id":5035,"links":{},"metadata":{"_buckets":{"deposit":"abb55486-9f4c-440d-b8e6-48bc17dcdb80"},"_deposit":{"created_by":2,"id":"5035","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"5035"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00005035","sets":["14:21"]},"author_link":["20728","20727","20730","20729"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"1133","bibliographicPageStart":"1121","bibliographicVolumeNumber":"88","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to estimate the free energy barrier to rotation around the C1-C11 single bond in lamellarins, new lamellarin analogues (1a), (1b), (2a), and (2b) possessing diastereotopic protons or carbons at the C1 aryl moiety were synthesized. Variable-temperature 1H and 13C NMR measurements of these analogues revealed that the free energy barriers to rotation around the C1-C11 axis in 5,6-saturated and 5,6-unsaturated lamellarins were around 72-74 and 83-87 kJ/mol, respectively.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES, 88(2), pp.1121-1133; 2014","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本複素環化学研究所"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3987/COM-13-S(S)69","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2014 The Japan Institute of Heterocyclic Chemistry"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03855414","subitem_source_identifier_type":"ISSN"}]},"item_2_text_62":{"attribute_name":"出版者別言語","attribute_value_mlt":[{"subitem_text_value":"Japan Institute of Heterocyclic Chemistry"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Fukuda, Tsutomu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Itoyama, Ryosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Minagawa, Terufusa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Iwao, Masatomo"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"supporting info.pdf","filesize":[{"value":"3.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"supporting info.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/5035/files/supporting info.pdf"},"version_id":"cb1ea588-ef7e-45e6-9cf7-0986e1a6e592"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"Het88_1121.pdf","filesize":[{"value":"916.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Het88_1121.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/5035/files/Het88_1121.pdf"},"version_id":"9415c047-d1f4-42a9-81fe-080ff5d28344"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Rotational Energy Barrier around the C1?C11 Single Bond in Lamellarins: A Study by Variable-Temperature NMR","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Rotational Energy Barrier around the C1?C11 Single Bond in Lamellarins: A Study by Variable-Temperature NMR"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-01-23"},"publish_date":"2014-01-23","publish_status":"0","recid":"5035","relation_version_is_last":true,"title":["Rotational Energy Barrier around the C1?C11 Single Bond in Lamellarins: A Study by Variable-Temperature NMR"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T03:12:53.995458+00:00"}