@article{oai:nagasaki-u.repo.nii.ac.jp:00005521, author = {Arikawa, Yasuhiro and Yamaguchi, Soseki and Haige, Ryohei and Oshiro, Eriko and Umakoshi, Keisuke and Onishi, Masayoshi}, journal = {Journal of Organometallic Chemistry}, month = {Apr}, note = {Reaction of [TpRuCl2(NO)] (1) (Tp = HB(pyrazol-1-yl) 3) with dimethylzinc, Zn(Me)2, gave rise to a dimethyl complex [TpRu(Me)2(NO)] (2) and a monomethyl complex [TpRuCl(Me)(NO)] (3) in good yields, while the use of a Grignard reagent, MeMgCl, as the alkylating agents led to isolation of 2 in low yield. Complexes 2 and 3 were confirmed by single-crystal X-ray diffraction analyses. Treatment of 2 with triflic acid, CF3SO3H, afforded a triflato complex [TpRu(Me){OS(O)2CF3}(NO)] (4)., Journal of Organometallic Chemistry, 755, pp.12-15; 2014}, pages = {12--15}, title = {Methylation of a nitrosylruthenium complex bearing a hydridotris(pyrazolyl)borate ligand}, volume = {755}, year = {2014} }