{"created":"2023-05-15T16:33:19.887454+00:00","id":5521,"links":{},"metadata":{"_buckets":{"deposit":"693ca1c2-3607-4c17-8968-f6775090d71b"},"_deposit":{"created_by":2,"id":"5521","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"5521"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00005521","sets":["14:21"]},"author_link":["23527","23528","23531","23529","23530","23532"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-04-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"15","bibliographicPageStart":"12","bibliographicVolumeNumber":"755","bibliographic_titles":[{"bibliographic_title":"Journal of Organometallic Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Reaction of [TpRuCl2(NO)] (1) (Tp = HB(pyrazol-1-yl) 3) with dimethylzinc, Zn(Me)2, gave rise to a dimethyl complex [TpRu(Me)2(NO)] (2) and a monomethyl complex [TpRuCl(Me)(NO)] (3) in good yields, while the use of a Grignard reagent, MeMgCl, as the alkylating agents led to isolation of 2 in low yield. Complexes 2 and 3 were confirmed by single-crystal X-ray diffraction analyses. Treatment of 2 with triflic acid, CF3SO3H, afforded a triflato complex [TpRu(Me){OS(O)2CF3}(NO)] (4).","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Journal of Organometallic Chemistry, 755, pp.12-15; 2014","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jorganchem.2013.12.054","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2014 Elsevier B.V. All rights reserved."},{"subitem_rights":"NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, 755, (2014)"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022328X","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Arikawa, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamaguchi, Soseki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Haige, Ryohei"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Oshiro, Eriko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Umakoshi, Keisuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Onishi, Masayoshi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"JOC755_12.pdf","filesize":[{"value":"708.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JOC755_12.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/5521/files/JOC755_12.pdf"},"version_id":"a575fd19-4904-45b7-951f-6ca2f08eb23f"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Alkylation","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydridotris(pyrazolyl)borate","subitem_subject_scheme":"Other"},{"subitem_subject":"Nitrogen monoxide","subitem_subject_scheme":"Other"},{"subitem_subject":"Nitrosylruthenium","subitem_subject_scheme":"Other"},{"subitem_subject":"Protonolysis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Methylation of a nitrosylruthenium complex bearing a hydridotris(pyrazolyl)borate ligand","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Methylation of a nitrosylruthenium complex bearing a hydridotris(pyrazolyl)borate ligand"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-07-31"},"publish_date":"2014-07-31","publish_status":"0","recid":"5521","relation_version_is_last":true,"title":["Methylation of a nitrosylruthenium complex bearing a hydridotris(pyrazolyl)borate ligand"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T03:03:33.910632+00:00"}